Condensation of iso-butanal and tert-butyl alcohol catalyzed by bronsted acidic ionic liquids
文献类型：期刊论文
| 作者 | Shen Jianghan1,2; Wang Hua1; Sun Ying1,2; Liu Hongchao1,2; Liu Zhongmin1 |
| 刊名 | chinese journal of catalysis
 |
| 出版日期 | 2007-11-01 |
| 卷号 | 28期号:11页码:1009-1012 |
| 关键词 | ionic liquid Bronsted acid iso-butanal tert-butyl alcohol Prins condensation 2 5-dimethyl-2 4-hexadiene |
| 英文摘要 | catalytic synthesis of 2,5-dimethyl-2,4-hexadiene by prins condensation of iso-butanal and tert-butyl alcohol was investigated using bronsted acidic ionic liquids as both catalyst and solvent. it was found that all the ionic liquids were active for prins condensation. after reaction, the upper organic phase could be easily separated from the ionic liquid by decantation. the ionic liquids could be reused in the next run by heat treatment under vacuum. manipulating the structure of ionic liquids with respect to the organic cation or the organic/inorganic anion had great effects on the catalytic performance of the ionic liquids. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | prins condensation ; isobutyl aldehyde ; esterification ; green ; 2,5-dimethyl-2,4-hexadiene ; efficient ; system |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000251594300016 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/140666]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Grad Univ Beijing, Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Shen Jianghan,Wang Hua,Sun Ying,et al. Condensation of iso-butanal and tert-butyl alcohol catalyzed by bronsted acidic ionic liquids[J]. chinese journal of catalysis,2007,28(11):1009-1012. |
| APA | Shen Jianghan,Wang Hua,Sun Ying,Liu Hongchao,&Liu Zhongmin.(2007).Condensation of iso-butanal and tert-butyl alcohol catalyzed by bronsted acidic ionic liquids.chinese journal of catalysis,28(11),1009-1012. |
| MLA | Shen Jianghan,et al."Condensation of iso-butanal and tert-butyl alcohol catalyzed by bronsted acidic ionic liquids".chinese journal of catalysis 28.11(2007):1009-1012. |
入库方式： OAI收割
来源：大连化学物理研究所
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