Azadithiolates cofactor of the iron-only hydrogenase and its PR3-monosubstituted derivatives: Synthesis, structure, electrochemistry and protonation
文献类型：期刊论文
| 作者 | Wang, Zhen1; Liu, Jian-Hui1; He, Cheng-Jiang1; Jiang, Shi1; Akermark, Bjorn2; Sun, Li-Cheng1,3 |
| 刊名 | journal of organometallic chemistry
 |
| 出版日期 | 2007-11-15 |
| 卷号 | 692期号:24页码:5501-5507 |
| 关键词 | azapropanedithiolate phosphine ligand exchange iron-only hydrogenase |
| 英文摘要 | the core structure (mu-sch2)(2)nh[fe-2(co)(6)](5) of fe-only hydrogenases active site model has been synthesized by the condensation of iron carbonyl sulfides, formaldehyde and silyl protected amine. its monosubstituted complexes (mu-sch2)(2)nh[fe-2(co)(5)pr3] (r = ph (6), me (7)) were accordingly prepared. the coordination configurations of 5 and 6 were characterized by x-ray crystallography. protonation of complex 7 to form the n-protonated product occurs in an acetonitrile solution upon addition of triflic acid. the redox properties of these model complexes were studied by cyclic voltammetry. (c) 2007 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, inorganic & nuclear ; chemistry, organic |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | metal-carbonyl derivatives ; active-site ; model complexes ; tertiary ; coordination ; reduction ; chemistry ; evolution ; cluster ; ligand |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000253488400023 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/140718]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Fine Chem, Dalian 116012, Peoples R China 2.Stockholm Univ, Dept Organ Chem, S-10691 Stockholm, Sweden 3.Royal Inst Technol, KTH Chem Organ Chem, S-10044 Stockholm, Sweden |
| 推荐引用方式 GB/T 7714 | Wang, Zhen,Liu, Jian-Hui,He, Cheng-Jiang,et al. Azadithiolates cofactor of the iron-only hydrogenase and its PR3-monosubstituted derivatives: Synthesis, structure, electrochemistry and protonation[J]. journal of organometallic chemistry,2007,692(24):5501-5507. |
| APA | Wang, Zhen,Liu, Jian-Hui,He, Cheng-Jiang,Jiang, Shi,Akermark, Bjorn,&Sun, Li-Cheng.(2007).Azadithiolates cofactor of the iron-only hydrogenase and its PR3-monosubstituted derivatives: Synthesis, structure, electrochemistry and protonation.journal of organometallic chemistry,692(24),5501-5507. |
| MLA | Wang, Zhen,et al."Azadithiolates cofactor of the iron-only hydrogenase and its PR3-monosubstituted derivatives: Synthesis, structure, electrochemistry and protonation".journal of organometallic chemistry 692.24(2007):5501-5507. |
入库方式： OAI收割
来源：大连化学物理研究所
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