A spectroscopic study on singlet oxygen production from different reaction paths using solid inorganic peroxides as starting materials
文献类型：期刊论文
| 作者 | Li, Qingwei; Chen, Fang; Zhao, Weili; Xu, Mingxiu; Fang, Benjie; Zhang, Yuelong; Duo, Liping; Jin, Yuqi; Sang, Fengting |
| 刊名 | bulletin of the korean chemical society
 |
| 出版日期 | 2007-10-20 |
| 卷号 | 28期号:10页码:1656-1660 |
| 关键词 | singlet oxygen peroxides emission spectroscopy reactions chlorine |
| 英文摘要 | using solid inorganic peroxides (including li2o2, na2o2, sro2 and bao2) as starting materials, three reaction paths for singlet oxygen (o-1(2)) production were developed and studied. their o-1(2) emission spectra in the near-ir region and visible region from these reaction paths were simultaneously recorded by a near-ir sensitive optical multichannel analyzer and a visible sensitive optical spectrum analyzer, respectively. the comparison of their 102 emission spectra indicated that: (1) in term of the efficiency for 102 production, the gas-liquid-solid ;reaction path (in which cl-2 or hcl and h2o reacted with the solid inorganic peroxides suspension in ccl4) was prior to the gas-solid reaction path (in which cl-2 or hcl reacted with the solid inorganic peroxides suspension in ccl4), but was inferior to the gas-liquid reaction path (in which cl-2 or hcl reacted with the solid inorganic peroxides solution in h2o or d2o); (2) the alkali metal peroxides (such as li2o2 and na2o2) was prior to the alkaline earth metal peroxides (such as sro2 and bao2) as the solid reactants, and cl-2 was favorable than hcl as the gas reactant in efficiency for o-1(2) production in these reaction paths. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, multidisciplinary |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | efficiency factors ; solvent shift ; generation ; oxidation ; lifetime |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000251301600008 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/140722]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, Lab Chem Lasers, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Qingwei,Chen, Fang,Zhao, Weili,et al. A spectroscopic study on singlet oxygen production from different reaction paths using solid inorganic peroxides as starting materials[J]. bulletin of the korean chemical society,2007,28(10):1656-1660. |
| APA | Li, Qingwei.,Chen, Fang.,Zhao, Weili.,Xu, Mingxiu.,Fang, Benjie.,...&Sang, Fengting.(2007).A spectroscopic study on singlet oxygen production from different reaction paths using solid inorganic peroxides as starting materials.bulletin of the korean chemical society,28(10),1656-1660. |
| MLA | Li, Qingwei,et al."A spectroscopic study on singlet oxygen production from different reaction paths using solid inorganic peroxides as starting materials".bulletin of the korean chemical society 28.10(2007):1656-1660. |
入库方式： OAI收割
来源：大连化学物理研究所
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