Direct splitting of H(2)S into H(2) and S on CdS-based photocatalyst under visible light irradiation
文献类型：期刊论文
| 作者 | Ma, Guijun; Yan, Hongjian; Shi, Jingying; Zong, Xu; Lei, Zhibing; Li, Can |
| 刊名 | journal of catalysis
 |
| 出版日期 | 2008-11-15 |
| 卷号 | 260期号:1页码:134-140 |
| 关键词 | Cadmium sulfide Ethanolamine Polysulfide Hydrogen production Hydrogen sulfide conversion Photocatalysis Electrochemistry |
| 英文摘要 | the conversion of h(2)s into h(2) and s (h(2)s -> h(2) + s) is beneficial from both environmental and energy standpoints. here we report that h(2)s can be splitted stoichiometrically into hydrogen and sulfur on cds-based photocatalysts under visible light irradiation using ethanolamine as a h(2)s solvent and reaction media at room temperature. raman spectra showed that the produced sulfur existed as s(4)(2-) and s(6)(2-) after photocatalytic reaction. the hydroxyls of the reaction media were found to be crucial for the hydrogen production, and the rate-determining step (rds) of photocatalytic splitting h(2)s in diethanolamine is discussed. electrochemical evaluation showed that the potential of h(2)s splitting in ethanolamine was greatly lowered and the photogenerated electrons could be fully used to reduce protons for hydrogen production. a free-radical-related one-electron electrochemical oxidation process on platinum electrode is suggested. this work demonstrates the possibility of the direct splitting h(2)s into s and h(2) via photocatalysis. (c) 2008 elsevier inc. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | hydrogen-sulfide ; aqueous-solutions ; hydrosulfide ions ; water reduction ; liquid-ammonia ; oxidation ; sulfur ; polysulfides ; decomposition ; suspensions |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000261255000015 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/140772]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ma, Guijun,Yan, Hongjian,Shi, Jingying,et al. Direct splitting of H(2)S into H(2) and S on CdS-based photocatalyst under visible light irradiation[J]. journal of catalysis,2008,260(1):134-140. |
| APA | Ma, Guijun,Yan, Hongjian,Shi, Jingying,Zong, Xu,Lei, Zhibing,&Li, Can.(2008).Direct splitting of H(2)S into H(2) and S on CdS-based photocatalyst under visible light irradiation.journal of catalysis,260(1),134-140. |
| MLA | Ma, Guijun,et al."Direct splitting of H(2)S into H(2) and S on CdS-based photocatalyst under visible light irradiation".journal of catalysis 260.1(2008):134-140. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。