Olefins alkylation thiophenic sulfur of the real gasoline over the fluorinated Hbeta zeolite catalyst
文献类型:期刊论文
作者 | Zhang, Zekai1,2; Guo, Xiaoye3; Liu, Shenglin1; Zhu, Xiangxue1; Xu, Longya1 |
刊名 | fuel processing technology
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出版日期 | 2008-11-01 |
卷号 | 89期号:11页码:1135-1141 |
关键词 | Thiophenes Alkylation Gasoline Olefins content H beta-F |
英文摘要 | the efficiency of the catalytic alkylation, the first step of the olefins alkylation thiophenic sulfur (oats) process was investigated in three typical gasoline samples with different olefins contents over a fluorinated h beta zeolite catalyst. under the reaction conditions of 120 degrees c, 1.5 mpa and whsv 0.5 h(-1), over 95% light sulfur compounds in the feeds could be transformed to be heavier than the heptyl-thiophenes within a period of time-on-stream, the lifetime of the catalyst could prolong from 10 h to 26 h when the olefins content in the gasoline feed decreased from 40.87 wt.% to 9.20 wt% it was also found that the olefins content decrease was favorable for keeping and promoting the octane number by redistributing the components of the treated gasoline. in addition, the influence of the reaction conditions such as the temperature and whsv on the efficiency of the catalytic alkylation was investigated. (c) 2008 elsevier b.v. all rights reserved. |
WOS标题词 | science & technology ; physical sciences ; technology |
类目[WOS] | chemistry, applied ; energy & fuels ; engineering, chemical |
研究领域[WOS] | chemistry ; energy & fuels ; engineering |
关键词[WOS] | liquid-phase alkylation ; solid acid catalysts ; refinery streams ; desulfurization ; isopropanol ; naphthalene ; performance ; fuels |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000261281600018 |
公开日期 | 2015-11-17 |
源URL | [http://159.226.238.44/handle/321008/140789] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China 3.Dalian Polytech Univ, Dalian 116034, Liaoning, Peoples R China |
推荐引用方式 GB/T 7714 | Zhang, Zekai,Guo, Xiaoye,Liu, Shenglin,et al. Olefins alkylation thiophenic sulfur of the real gasoline over the fluorinated Hbeta zeolite catalyst[J]. fuel processing technology,2008,89(11):1135-1141. |
APA | Zhang, Zekai,Guo, Xiaoye,Liu, Shenglin,Zhu, Xiangxue,&Xu, Longya.(2008).Olefins alkylation thiophenic sulfur of the real gasoline over the fluorinated Hbeta zeolite catalyst.fuel processing technology,89(11),1135-1141. |
MLA | Zhang, Zekai,et al."Olefins alkylation thiophenic sulfur of the real gasoline over the fluorinated Hbeta zeolite catalyst".fuel processing technology 89.11(2008):1135-1141. |
入库方式: OAI收割
来源:大连化学物理研究所
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