Molar heat capacity and thermodynamic properties of 1,2-cyclohexane dicarboxylic anhydride [C8H10O3]
文献类型:期刊论文
作者 | Lv, X-C.2; Gao, X-H.2; Tan, Z. -C.1,3; Li, Y-S.3; Sun, L. -X.1 |
刊名 | journal of thermal analysis and calorimetry
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出版日期 | 2008-05-01 |
卷号 | 92期号:2页码:523-527 |
关键词 | adiabatic calorimetry 1 low-temperature heat capacity thermal analysis 2-cyclohexane dicarboxylic anhydride |
英文摘要 | the molar heat capacity c-p,c-m of 1,2-cyclohexane dicarboxylic anhydride was measured in the temperature range from t=80 to 390 k with a small sample automated adiabatic calorimeter. the melting point t-m, the molar enthalpy delta h-fus(m) and the entropy delta s-fus(m) of fusion for the compound were determined to be 303.80 k, 14.71 kj mol(-1) and 48.43 j k-1 mol(-1), respectively. the thermodynamic functions [h-t-h-273.15] and [s-t-s-273.15] were derived in the temperature range from t=80 to 3 85 k with temperature interval of 5 k. the thermal stability of the compound was investigated by differential scanning calorimeter (dsc) and thermogravimetry (tg), when the process of the mass-loss was due to the evaporation, instead of its thermal decomposition. |
WOS标题词 | science & technology ; physical sciences |
类目[WOS] | chemistry, analytical ; chemistry, physical |
研究领域[WOS] | chemistry |
关键词[WOS] | thermal-analysis ; temperature ; acid |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000255957400028 |
公开日期 | 2015-11-17 |
源URL | [http://159.226.238.44/handle/321008/140818] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Thermochem Lab, Dalian 116023, Peoples R China 2.Liaoning Shihua Univ, Sch Chem & Mat Sci, Fushun 113001, Peoples R China 3.Dalian Jiaotong Univ, Coll Environm Sci & Engn, Dalian 116028, Peoples R China |
推荐引用方式 GB/T 7714 | Lv, X-C.,Gao, X-H.,Tan, Z. -C.,et al. Molar heat capacity and thermodynamic properties of 1,2-cyclohexane dicarboxylic anhydride [C8H10O3][J]. journal of thermal analysis and calorimetry,2008,92(2):523-527. |
APA | Lv, X-C.,Gao, X-H.,Tan, Z. -C.,Li, Y-S.,&Sun, L. -X..(2008).Molar heat capacity and thermodynamic properties of 1,2-cyclohexane dicarboxylic anhydride [C8H10O3].journal of thermal analysis and calorimetry,92(2),523-527. |
MLA | Lv, X-C.,et al."Molar heat capacity and thermodynamic properties of 1,2-cyclohexane dicarboxylic anhydride [C8H10O3]".journal of thermal analysis and calorimetry 92.2(2008):523-527. |
入库方式: OAI收割
来源:大连化学物理研究所
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