Synthesis of Fe, Co, and Mn substituted AlPO-5 molecular sieves and their catalytic activities in the selective oxidation of cyclohexane
文献类型：期刊论文
| 作者 | Zhou, Lipeng; Xu, Jie; Chen, Chen; Wang, Feng; Li, Xiaoqiang |
| 刊名 | journal of porous materials
 |
| 出版日期 | 2008-02-01 |
| 卷号 | 15期号:1页码:7-12 |
| 关键词 | molecular sieves aluminophosphate cyclohexane oxidation molecular oxygen |
| 英文摘要 | fe, co, and mn substituted alpo-5 molecular sieves, including feapo-5, coapo-5, mnapo-5, fecoapo-5, femnapo-5, and comnapo-5 were synthesized by hydrothermal method and characterized by x-ray diffraction (xrd), x-ray fluorescence (xrf), scanning electron microscopy (sem), nitrogen adsorption, and fourier transform infrared (ft-ir) spectroscopy. the lattice expansions were observed with fe, co, and/or mn substitution of al atom in alpo-5. the selective oxidation of cyclohexane to cyclohexanone and cyclohexanol (k/a oil) with molecular oxygen was studied over these catalysts at the reaction temperature of 403 k. the higher activities of the multi-metal substituted alpo-5, compared to that of single metal substituted alpo-5, were observed. the underlying reason for the superior activity of the multi-metal substituted alpo-5 was analyzed. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; materials science, multidisciplinary |
| 研究领域[WOS] | chemistry ; materials science |
| 关键词[WOS] | low conversion autoxidation ; transition-metal ions ; pure cyclohexane ; liquid-phase ; oxygen ; aluminophosphate ; hydrocarbons ; air ; vapo-5 |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000251795500002 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/140843]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, Grad Sch, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhou, Lipeng,Xu, Jie,Chen, Chen,et al. Synthesis of Fe, Co, and Mn substituted AlPO-5 molecular sieves and their catalytic activities in the selective oxidation of cyclohexane[J]. journal of porous materials,2008,15(1):7-12. |
| APA | Zhou, Lipeng,Xu, Jie,Chen, Chen,Wang, Feng,&Li, Xiaoqiang.(2008).Synthesis of Fe, Co, and Mn substituted AlPO-5 molecular sieves and their catalytic activities in the selective oxidation of cyclohexane.journal of porous materials,15(1),7-12. |
| MLA | Zhou, Lipeng,et al."Synthesis of Fe, Co, and Mn substituted AlPO-5 molecular sieves and their catalytic activities in the selective oxidation of cyclohexane".journal of porous materials 15.1(2008):7-12. |
入库方式： OAI收割
来源：大连化学物理研究所
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