Enantioselective synthesis of optically active alkanephosphonates via rhodium-catalyzed asymmetric hydrogenation of beta-substituted alpha,beta-unsaturated phosphonates with ferrocene-based monophosphoramidite ligands
文献类型：期刊论文
| 作者 | Duan, Zheng-Chao1,2; Hu, Xiang-Ping1; Wang, Dao-Yong1,2; Huang, Jia-Di1,2; Yu, Sai-Bo1,2; Deng, Jun1,2; Zheng, Zhuo1 |
| 刊名 | advanced synthesis & catalysis
 |
| 出版日期 | 2008-09-01 |
| 卷号 | 350期号:13页码:1979-1983 |
| 关键词 | alkanephosphonates asymmetric catalysis hydrogenation monophosphoramidite ligands rhodium |
| 英文摘要 | a series of chiral beta-substituted alkane-phosphonates was synthesized in high enantioselectivities via the first rhodium-catalyzed asymmetric hydrogenation of the corresponding beta-substituted-alpha,beta-unsaturated phosphonates using a ferrocene-derived rnonophosphoramidite ligand, with which up to 99.5% ee have been achieved for the hydrogenation of (e)-substrates and 98.0% ee for (z)-substrates. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, applied ; chemistry, organic |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | phosphine-phosphoramidite ligands ; dehydroamino acid-derivatives ; photo-arbuzov rearrangements ; enol ester phosphonates ; n-h proton ; amino acids ; reactive immunization ; benzyl phosphites ; micellar media ; alpha-hydroxy |
| 收录类别 | SCI ; IC |
| 语种 | 英语 |
| WOS记录号 | WOS:000259544300010 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/140854]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Duan, Zheng-Chao,Hu, Xiang-Ping,Wang, Dao-Yong,et al. Enantioselective synthesis of optically active alkanephosphonates via rhodium-catalyzed asymmetric hydrogenation of beta-substituted alpha,beta-unsaturated phosphonates with ferrocene-based monophosphoramidite ligands[J]. advanced synthesis & catalysis,2008,350(13):1979-1983. |
| APA | Duan, Zheng-Chao.,Hu, Xiang-Ping.,Wang, Dao-Yong.,Huang, Jia-Di.,Yu, Sai-Bo.,...&Zheng, Zhuo.(2008).Enantioselective synthesis of optically active alkanephosphonates via rhodium-catalyzed asymmetric hydrogenation of beta-substituted alpha,beta-unsaturated phosphonates with ferrocene-based monophosphoramidite ligands.advanced synthesis & catalysis,350(13),1979-1983. |
| MLA | Duan, Zheng-Chao,et al."Enantioselective synthesis of optically active alkanephosphonates via rhodium-catalyzed asymmetric hydrogenation of beta-substituted alpha,beta-unsaturated phosphonates with ferrocene-based monophosphoramidite ligands".advanced synthesis & catalysis 350.13(2008):1979-1983. |
入库方式： OAI收割
来源：大连化学物理研究所
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