Pt/MnOx-CeO2 catalysts for the complete oxidation of formaldehyde at ambient temperature
文献类型：期刊论文
| 作者 | Tang, Xingfu; Chen, Junli; Huang, Xiumin; Xu, Yide; Shen, Wenjie |
| 刊名 | applied catalysis b-environmental
 |
| 出版日期 | 2008-05-30 |
| 卷号 | 81期号:1-2页码:115-121 |
| 关键词 | MnOx-CeO2 mixed oxides Pt/MnOx-CeO2 catalyst complete oxidation formaldehyde platinum precursor |
| 英文摘要 | mnox-ceo2 mixed oxides with a mn/(mn + ce) molar ratios of 0-1 were prepared by a modified coprecipitation method and investigated for the complete oxidation of formaldehyde. the mnox-ceo2 with mn/(mn + ce) molar ratio of 0.5 exhibited the highest catalytic activity among the mnox-ceo2 mixed oxides. structure analysis by x-ray powder diffraction and temperature-programmed reduction of hydrogen revealed that the formation of mnox-ceo2 solid solution greatly improved the low-temperature reducibility, resulting in a higher catalytic activity for the oxidation of formaldehyde. promoting effect of pt on the mnox-ceo2 mixed oxide indicated that both the pt precursors and the reduction temperature greatly affected the catalytic performance. pt/mnox-ceo2 catalyst prepared from chlorine-free precursor showed extremely high activity and stability after pretreatment with hydrogen at 473 k. 100% conversion of formaldehyde was achieved at ambient temperature and no deactivation was observed for 120 h time-on-stream. the promoting effect of pt was ascribed to enhance the effective activation of oxygen molecule on the mnox-ceo2 support. (c) 2007 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, physical ; engineering, environmental ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | wet-oxidation ; room-temperature ; cerium oxide ; pt/al2o3 catalysts ; pt/tio2 catalyst ; indoor air ; adsorption ; chlorine ; combustion ; reduction |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000256603200012 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/140861]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Tang, Xingfu,Chen, Junli,Huang, Xiumin,et al. Pt/MnOx-CeO2 catalysts for the complete oxidation of formaldehyde at ambient temperature[J]. applied catalysis b-environmental,2008,81(1-2):115-121. |
| APA | Tang, Xingfu,Chen, Junli,Huang, Xiumin,Xu, Yide,&Shen, Wenjie.(2008).Pt/MnOx-CeO2 catalysts for the complete oxidation of formaldehyde at ambient temperature.applied catalysis b-environmental,81(1-2),115-121. |
| MLA | Tang, Xingfu,et al."Pt/MnOx-CeO2 catalysts for the complete oxidation of formaldehyde at ambient temperature".applied catalysis b-environmental 81.1-2(2008):115-121. |
入库方式： OAI收割
来源：大连化学物理研究所
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