Heat capacities and thermodynamic properties of trans-(R)-3-(2,2-dichloroethenyl)-2,2-dimethylcyclopropanecarboxylic acid
文献类型：期刊论文
| 作者 | Xue, B.1; Li, X. -F.1; Wang, J. -Y.1; Yu, S. -J.1; Tan, Z. -C.2; Sun, L. -X.2 |
| 刊名 | journal of thermal analysis and calorimetry
 |
| 出版日期 | 2008-11-01 |
| 卷号 | 94期号:2页码:529-534 |
| 关键词 | adiabatic calorimetry heat capacity thermal decomposition thermodynamic function trans-(R)-3-(2 2-dichloroethenyl)-2 2-dimethylcyclopropanecarboxylic acid |
| 英文摘要 | the heat capacities of trans-(r)-3-(2,2-dichloroethenyl)-2,2-dimethylcyclopropanecarboxylic acid in the temperature range from 78 to 389 k were measured with a precise automatic adiabatic calorimeter. the sample was prepared with the purity of 0.9874 mole fraction. a solid-liquid fusion phase transition was observed in the experimental temperature range. the melting point, t (m), enthalpy and entropy of fusion, delta(fus)h(m), delta(fus)s(m), were determined to be 344.75 +/- 0.02 k, 13.75 +/- 0.07 kj mol(-1), 39.88 +/- 0.21 j k(-1) mol(-1), respectively. the thermodynamic functions of the sample, h ((t))-h ((298.15)), s ((t))-s ((298.15)) and g ((t))-g ((298.15)), were reported with a temperature interval of 5 k. the thermal decomposition of the sample was studied by tg analysis, the thermal decomposition starts at ca. 421 k and terminates at ca. 535 k, the maximum decomposition rate was obtained at 525 k. the order of reaction, pre-exponential factor and activation energy, are n=0.14, a=1.15 center dot 10(8) min(-1), e=66.27 kj mol(-1), respectively. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, analytical ; chemistry, physical |
| 研究领域[WOS] | chemistry |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000260878000032 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/140862]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Shenyang Univ Technol, Sch Petrochem Engn, Liaoyang 111003, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Thermochem Lab, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xue, B.,Li, X. -F.,Wang, J. -Y.,et al. Heat capacities and thermodynamic properties of trans-(R)-3-(2,2-dichloroethenyl)-2,2-dimethylcyclopropanecarboxylic acid[J]. journal of thermal analysis and calorimetry,2008,94(2):529-534. |
| APA | Xue, B.,Li, X. -F.,Wang, J. -Y.,Yu, S. -J.,Tan, Z. -C.,&Sun, L. -X..(2008).Heat capacities and thermodynamic properties of trans-(R)-3-(2,2-dichloroethenyl)-2,2-dimethylcyclopropanecarboxylic acid.journal of thermal analysis and calorimetry,94(2),529-534. |
| MLA | Xue, B.,et al."Heat capacities and thermodynamic properties of trans-(R)-3-(2,2-dichloroethenyl)-2,2-dimethylcyclopropanecarboxylic acid".journal of thermal analysis and calorimetry 94.2(2008):529-534. |
入库方式： OAI收割
来源：大连化学物理研究所
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