Preparation, characterization and activities of the nano-sized Ni/SBA-15 catalyst for producing COx-free hydrogen from ammonia
文献类型：期刊论文
| 作者 | Liu, Hongchao1,2; Wang, Hua1; Shen, Jianghan1,2; Sun, Ying1,2; Liu, Zhongmin1 |
| 刊名 | applied catalysis a-general
 |
| 出版日期 | 2008-03-25 |
| 卷号 | 337期号:2页码:138-147 |
| 关键词 | deposition-precipitation method Ni/SBA-15 COx-free hydrogen ammonia decomposition |
| 英文摘要 | ni/sba-15 catalysts that are used in ammonia decomposition to produce cox-free hydrogen were prepared by a deposition-precipitation (dp) method and investigated by n-2 adsorption/desorption, xrd, tem and h-2-tpr techniques. the results show that not only the nano-sized nickel particles with narrow distribution could be obtained, but also the ordered mesostructures of the ni/sba-15. catalysts could be achieved during the preparation process. the amount of formed nickel phyllosilicate increases with prolonging the dp time, while surface areas and pore sizes of samples decrease relatively. these ni/sba-15 catalysts exhibit higher performance than other ni-based catalysts and even some supported ru catalysts. ammonia conversion is more than 96% at 873 k with ghsv(nh3) of 46,000 ml/h g-cat. additionally, the ni/sba-15 catalyst is very stable during catalytic evaluation operation due to the strong interactions between nickel grains and sba-15 support. (c) 2007 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; life sciences & biomedicine |
| 类目[WOS] | chemistry, physical ; environmental sciences |
| 研究领域[WOS] | chemistry ; environmental sciences & ecology |
| 关键词[WOS] | temperature-programmed-reduction ; fuel-cell applications ; deposition-precipitation ; oxidative dehydrogenation ; supported catalysts ; nh3 decomposition ; ni(ii) phase ; nickel-oxide ; silica ; generation |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000255618800004 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/140865]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Lab Appl Catalysis, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Hongchao,Wang, Hua,Shen, Jianghan,et al. Preparation, characterization and activities of the nano-sized Ni/SBA-15 catalyst for producing COx-free hydrogen from ammonia[J]. applied catalysis a-general,2008,337(2):138-147. |
| APA | Liu, Hongchao,Wang, Hua,Shen, Jianghan,Sun, Ying,&Liu, Zhongmin.(2008).Preparation, characterization and activities of the nano-sized Ni/SBA-15 catalyst for producing COx-free hydrogen from ammonia.applied catalysis a-general,337(2),138-147. |
| MLA | Liu, Hongchao,et al."Preparation, characterization and activities of the nano-sized Ni/SBA-15 catalyst for producing COx-free hydrogen from ammonia".applied catalysis a-general 337.2(2008):138-147. |
入库方式： OAI收割
来源：大连化学物理研究所
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