The gas permeation properties of 6FDA-2, 4, 6-trimethyl-1, 3-phenylenediamine (TMPDA)/1, 3-phenylenediamine (mPDA) copolyimides
文献类型：期刊论文
| 作者 | Wang, Lina1,2; Cao, Yiming1; Zhou, Meiqing1; Ding, Xiaoli1,2; Liu, Qinhua1; Yuan, Quan1 |
| 刊名 | polymer bulletin
 |
| 出版日期 | 2008-02-01 |
| 卷号 | 60期号:1页码:137-147 |
| 关键词 | 6FDA copolyimide permeability gas separation |
| 英文摘要 | the gas permeation behavior of 2, 2'-bis (3, 4'dicarboxyphenyl) hexafluoropropane dianhydride(6fda)- 2, 4, 6-trimethyl-1, 3-phenylenediamine (tmpda)/1,3-phenylenediamine (mpda) polyimides was investigated by systematically varying the diamine ratios. the physical properties of the copolyimides were characterized by ir, dsc and tga. all the copolyimides were soluble in most of the common solvents. the gas permeabilities and diffusion coefficients decreased with increasing mpda content; however, the permselectivity of gas pairs such as h-2/n-2, o-2/n-2, co2/ch4 was enhanced with the incorporation of mpda moiety. the permeability coefficients of h-2, o-2, n-2, co2 and ch4 were found to decrease with the increasing order of kinetic diameters of the penetrant gases. moreover, all of the copolyimides studied in this work exhibited performance near, lying on or above the existing upper bound trade-off line between permselectivity and permeability. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | polymer science |
| 研究领域[WOS] | polymer science |
| 关键词[WOS] | asymmetric hollow-fiber ; transport properties ; permeability ; separation ; polyimides ; membranes ; polymers ; permselectivity ; diamines ; blends |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000252224100015 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/140882]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Chinese Acad Sci, China Grad Univ, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Lina,Cao, Yiming,Zhou, Meiqing,et al. The gas permeation properties of 6FDA-2, 4, 6-trimethyl-1, 3-phenylenediamine (TMPDA)/1, 3-phenylenediamine (mPDA) copolyimides[J]. polymer bulletin,2008,60(1):137-147. |
| APA | Wang, Lina,Cao, Yiming,Zhou, Meiqing,Ding, Xiaoli,Liu, Qinhua,&Yuan, Quan.(2008).The gas permeation properties of 6FDA-2, 4, 6-trimethyl-1, 3-phenylenediamine (TMPDA)/1, 3-phenylenediamine (mPDA) copolyimides.polymer bulletin,60(1),137-147. |
| MLA | Wang, Lina,et al."The gas permeation properties of 6FDA-2, 4, 6-trimethyl-1, 3-phenylenediamine (TMPDA)/1, 3-phenylenediamine (mPDA) copolyimides".polymer bulletin 60.1(2008):137-147. |
入库方式： OAI收割
来源：大连化学物理研究所
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