SYNTHESIS OF PERFLUOROSULFONATE IONOMER-STABILIZED PLATINUM COLLOID AND ITS APPLICATION IN DIRECT METHANOL FUEL CELLS
文献类型：期刊论文
| 作者 | Jiang, L.1; Sun, G. Q.1; Wang, Q.1; Xin, Q.1,2 |
| 刊名 | chemical industry & chemical engineering quarterly
 |
| 出版日期 | 2008-04-01 |
| 卷号 | 14期号:2页码:137-143 |
| 关键词 | Pt colloid perfluorosulfonate ionomer direct methanol fuel cell cathode electrocalalyst |
| 英文摘要 | pt colloid was synthesized by the reduction of hexachloroplatinic acid with formaldehyde in the presence of a stabilizer (a cation-exchanged polymer - perfluorosulfonate ionomer (pfsi) or teflon) or without any stabilizers. the average size of platinum particles with a stabilizer, characterized by a transmission electron microscopy and x-ray diffraction, is in a nanometer range in comparison with the particle agglomeration without any stabilizers. highly dispersive 40 wt. % pt/c catalyst obtained from the pfsi-stabilized pt colloid shows much better performance than its counterpart with teflon as a stabilizer or without any stabilizer according to the cyclic voltammetric (cv) characterization and the single direct methanol fuel cell (dmfc) performance testing. it is strongly suggested that the proton-conducting ionomer could smooth the reaction pathway by facilitating the proton transport, while teflon inhibit the active sites, though both of them can inhibit the particle growth. the improved fuel cell performance is attributed to the small particles and the unhindered transport of protons/-electrons ascribed to the intimate contact of pt and proton-conducting ionomer |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, applied ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | ptru alloy colloids ; high relative performance ; anode catalyst ; electrooxidation ; oxidation ; electrocatalysts ; precursors ; nanoparticles ; clusters ; co |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000262366800008 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/140895]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Direct Alcohol Fuel Cell Lab, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jiang, L.,Sun, G. Q.,Wang, Q.,et al. SYNTHESIS OF PERFLUOROSULFONATE IONOMER-STABILIZED PLATINUM COLLOID AND ITS APPLICATION IN DIRECT METHANOL FUEL CELLS[J]. chemical industry & chemical engineering quarterly,2008,14(2):137-143. |
| APA | Jiang, L.,Sun, G. Q.,Wang, Q.,&Xin, Q..(2008).SYNTHESIS OF PERFLUOROSULFONATE IONOMER-STABILIZED PLATINUM COLLOID AND ITS APPLICATION IN DIRECT METHANOL FUEL CELLS.chemical industry & chemical engineering quarterly,14(2),137-143. |
| MLA | Jiang, L.,et al."SYNTHESIS OF PERFLUOROSULFONATE IONOMER-STABILIZED PLATINUM COLLOID AND ITS APPLICATION IN DIRECT METHANOL FUEL CELLS".chemical industry & chemical engineering quarterly 14.2(2008):137-143. |
入库方式： OAI收割
来源：大连化学物理研究所
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