La0.4Ce0.6O1.8-La0.8Sr0.2MnO3-8 mol% yttria-stabilized zirconia composite cathode for anode-supported solid oxide fuel cells
文献类型:期刊论文
作者 | Zhang, Min1,2; Yang, Min1,2; Liu, Bin1,2; Hou, Zhifang1; Dong, Yonglai1; Cheng, Mojie1 |
刊名 | journal of power sources
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出版日期 | 2008-01-10 |
卷号 | 175期号:2页码:739-748 |
关键词 | composite cathode La0.4Ce0.6O1.8 La0.8Sr0.2MnO3 solid oxide fuel cells |
英文摘要 | the composite cathodes of la0.4ce0.6o1.8 (ldc)-la0.8sr0.2mno3 (lsm)-8 mol% yttria-stabilized zirconia (ysz) with different ldc contents were investigated for anode-supported solid oxide fuel cells with thin film ysz electrolyte. the oxygen temperature-programmed desorption profiles of the ldc-lsm-ysz composites indicate that the addition of ldc increases surface oxygen vacancies. the cell performance was improved largely after the addition of ldc, and the best cell performance was achieved on the cells with the composite cathodes containing 10 wt% or 15 wt% ldc. the electrode polarization resistance was reduced significantly after the addition of ldc. at 800 degrees c and 650 degrees c, the polarization resistances of the cell with a 10 wt% ldc composite cathode are 70% and 40% of those of the cell with a lsm-ysz composite cathode, respectively. the impedance spectra show that the processes associated with the dissociative adsorption of oxygen and diffusion of oxygen intermediates and/or oxygen ions on lsm surface and transfer of oxygen species at triple phase boundaries are accelerated after the addition of ldc. (c) 2007 elsevier b.v. all rights reserved. |
WOS标题词 | science & technology ; physical sciences ; technology |
类目[WOS] | electrochemistry ; energy & fuels |
研究领域[WOS] | electrochemistry ; energy & fuels |
关键词[WOS] | perovskite-type oxides ; temperature sofcs ; methane oxidation ; high-performance ; electrolyte ; nonstoichiometry ; laco1-xfexo3 ; interlayer ; exchange |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000252634300005 |
公开日期 | 2015-11-17 |
源URL | [http://159.226.238.44/handle/321008/140926] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Zhang, Min,Yang, Min,Liu, Bin,et al. La0.4Ce0.6O1.8-La0.8Sr0.2MnO3-8 mol% yttria-stabilized zirconia composite cathode for anode-supported solid oxide fuel cells[J]. journal of power sources,2008,175(2):739-748. |
APA | Zhang, Min,Yang, Min,Liu, Bin,Hou, Zhifang,Dong, Yonglai,&Cheng, Mojie.(2008).La0.4Ce0.6O1.8-La0.8Sr0.2MnO3-8 mol% yttria-stabilized zirconia composite cathode for anode-supported solid oxide fuel cells.journal of power sources,175(2),739-748. |
MLA | Zhang, Min,et al."La0.4Ce0.6O1.8-La0.8Sr0.2MnO3-8 mol% yttria-stabilized zirconia composite cathode for anode-supported solid oxide fuel cells".journal of power sources 175.2(2008):739-748. |
入库方式: OAI收割
来源:大连化学物理研究所
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