Base-base bifunctional catalysis: A practical strategy for asymmetric Michael addition of malonates to alpha,beta-unsaturated aldehydes
文献类型：期刊论文
| 作者 | Wang, Yongcan1; Li, Pengfei1; Liang, Xinmiao1,2; Ye, Jinxing1,2 |
| 刊名 | advanced synthesis & catalysis
 |
| 出版日期 | 2008-06-01 |
| 卷号 | 350期号:9页码:1383-1389 |
| 关键词 | aldehydes asymmetric catalysis bifunctional catalysis malonates Michael addition |
| 英文摘要 | lewis base-bronsted base bifunctional catalysis is a novel and practical strategy for the asymmetric michael addition. the addition of malonates to a series of cc,p-unsaturated aldehydes can take place under base-base bifunctional catalytic conditions using 0.5-5 mol% of (s)-2-[diphenyl(trimethyl-silyloxy)methyl]pyrrolidine as catalyst and 5-30 mol% of lithium 4-fluorobenzoate as additive base with up to 99% ee. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, applied ; chemistry, organic |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | organocatalytic conjugate addition ; enantioselective michael ; cinchona alkaloids ; organic catalysis ; iminium catalysis ; mannich reaction ; c-c ; proline ; derivatives ; aldol |
| 收录类别 | SCI ; IC ; CCR |
| 语种 | 英语 |
| WOS记录号 | WOS:000256976100031 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/140928]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.E China Univ Sci & Technol, Sch Pharm, Minist Educ, Engn Res Ctr Pharmaceut Proc Chem, Shanghai 200237, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Yongcan,Li, Pengfei,Liang, Xinmiao,et al. Base-base bifunctional catalysis: A practical strategy for asymmetric Michael addition of malonates to alpha,beta-unsaturated aldehydes[J]. advanced synthesis & catalysis,2008,350(9):1383-1389. |
| APA | Wang, Yongcan,Li, Pengfei,Liang, Xinmiao,&Ye, Jinxing.(2008).Base-base bifunctional catalysis: A practical strategy for asymmetric Michael addition of malonates to alpha,beta-unsaturated aldehydes.advanced synthesis & catalysis,350(9),1383-1389. |
| MLA | Wang, Yongcan,et al."Base-base bifunctional catalysis: A practical strategy for asymmetric Michael addition of malonates to alpha,beta-unsaturated aldehydes".advanced synthesis & catalysis 350.9(2008):1383-1389. |
入库方式： OAI收割
来源：大连化学物理研究所
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