中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Influence of chemical states of Au on CO oxidation over Au/CoCeOx catalyst

文献类型:期刊论文

作者Ta Na1; Zhang Milin1; Li Juan2; Li Huaju2; Shen Wenjie2
刊名chinese journal of catalysis
出版日期2008-08-01
卷号29期号:8页码:777-782
关键词cobalt oxide ceria composite oxide gold chemical state carbon monoxide low temperature oxidation
英文摘要au/coceox catalysts were prepared by i deposition-precipitation method. au chemical states were controlled by varying the temperature of pretreatment in an oxygen-containing atmosphere. the catalysts were characterized by powder x-ray diffraction, high-resolution transmission electron microscopy, temperature-programmed reduction, and x-ray photoelectron spectroscopy. the catalytic performance for co oxidation was investigated at ambient temperature. it was found that the conversion of co increased with increasing amount of au+ in the catalyst, and thus the cationic gold (au+) was considered the main active species. addition of water vapor to the feed gas promoted co conversion to some degree, but the catalytic performance decreased rapidly due to the disproportionation of au+ to au3+ and au-0 particularly for the catalyst that contained relatively large amounts of au+ species.
WOS标题词science & technology ; physical sciences ; technology
类目[WOS]chemistry, applied ; chemistry, physical ; engineering, chemical
研究领域[WOS]chemistry ; engineering
关键词[WOS]pretreatment conditions ; temperature oxidation ; carbon-monoxide ; nanoparticles ; performance ; au/tio2
收录类别SCI
语种英语
WOS记录号WOS:000259341000019
公开日期2015-11-17
源URL[http://159.226.238.44/handle/321008/140935]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位1.Harbin Engn Univ, Coll Mat Sci & Chem Engn, Harbin 150001, Heilongjiang, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China
推荐引用方式
GB/T 7714
Ta Na,Zhang Milin,Li Juan,et al. Influence of chemical states of Au on CO oxidation over Au/CoCeOx catalyst[J]. chinese journal of catalysis,2008,29(8):777-782.
APA Ta Na,Zhang Milin,Li Juan,Li Huaju,&Shen Wenjie.(2008).Influence of chemical states of Au on CO oxidation over Au/CoCeOx catalyst.chinese journal of catalysis,29(8),777-782.
MLA Ta Na,et al."Influence of chemical states of Au on CO oxidation over Au/CoCeOx catalyst".chinese journal of catalysis 29.8(2008):777-782.

入库方式: OAI收割

来源:大连化学物理研究所

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