Low-temperature heat capacities and thermochemistry properties of Sm(Val)Cl-3 center dot 6H(2)O
文献类型：期刊论文
| 作者 | Zhang Jing-Nan1,3; Tan Zhi-Cheng1; Liu Bei-Ping2; Shi Quan1; Tong Bo1 |
| 刊名 | acta physico-chimica sinica
 |
| 出版日期 | 2008-08-01 |
| 卷号 | 24期号:8页码:1378-1382 |
| 关键词 | rare-earth complex Sm(Val)Cl3 center dot 6H(2)O low-temperature heat capacity thermodynamic functions TG analysis |
| 英文摘要 | heat capacities of the complex of rare-earth element with valine [sm(val)cl3 center dot 6h(2)o] were measured with a high-precision automatic adiabatic calorimeter over the temperature range from 80 to 376 k, and the thermodynamic unctions (h-t-h-298.15 and s-t-s-298.15) were calculated. a large step in heat capacity was detected around 308 k and this may be attributed to a glass transition corresponding to freezing of structural disorder. thermal decomposition of this complex as studied by thermogravimetric (tg) technique and a possible mechanism for the decomposition was suggested. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | thermodynamic properties ; thermal-decomposition ; glass-transition ; crystalline ; re ; nd |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000259171000009 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/140975]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Thermochem Lab, Dalian 116023, Liaoning Prov, Peoples R China 2.Hunan Univ Arts & Sci, Dept Chem & Chem Engn, Changde 415000, Hunan, Peoples R China 3.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang Jing-Nan,Tan Zhi-Cheng,Liu Bei-Ping,et al. Low-temperature heat capacities and thermochemistry properties of Sm(Val)Cl-3 center dot 6H(2)O[J]. acta physico-chimica sinica,2008,24(8):1378-1382. |
| APA | Zhang Jing-Nan,Tan Zhi-Cheng,Liu Bei-Ping,Shi Quan,&Tong Bo.(2008).Low-temperature heat capacities and thermochemistry properties of Sm(Val)Cl-3 center dot 6H(2)O.acta physico-chimica sinica,24(8),1378-1382. |
| MLA | Zhang Jing-Nan,et al."Low-temperature heat capacities and thermochemistry properties of Sm(Val)Cl-3 center dot 6H(2)O".acta physico-chimica sinica 24.8(2008):1378-1382. |
入库方式： OAI收割
来源：大连化学物理研究所
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