Investigation of SM0.5Sr0.5CoO3-delta/Co3O4 composite cathode for intermediate-temperature solid oxide fuel cells
文献类型：期刊论文
| 作者 | Zhang, Haizhou; Liu, Huanying; Cong, You; Yang, Weishen |
| 刊名 | journal of power sources
 |
| 出版日期 | 2008-10-15 |
| 卷号 | 185期号:1页码:129-135 |
| 关键词 | IT-SOFC Co3O4 SSC Composite cathode Polarization resistance |
| 英文摘要 | the electrochemical properties of an sm0.5sr0.5coo3-delta/co3o (ssc/co3o4) composite cathode were investigated as a function of the cathode-firing temperature, ssc/co3o4 composition, oxygen partial pressure and co2 treatment. the results showed that the composite cathodes had an optimal microstructure at a firing temperature of about 1100 degrees c, while the optimum co3o4 content in the composite cathode was about40 wt.%. a single cell with this optimized c-40-1100 cathode exhibited a very low polarization resistance of 0.058 omega cm(2), and yielded a maximum power density of 1092 mw cm(-2) with humidified hydrogen fuel and air oxidant at 600 degrees c. the maximum power density reached 1452 mw cm(-2) when pure oxygen was used as the oxidant for a cell with a c-30-1100 cathode operating at 600 degrees c due to the enhanced open-circuit voltage and accelerated oxygen surface-exchange rate. x-ray diffraction and thermogravimetric analyses, as well as the electrochemical properties of a co2-treated cathode, also implied promising applications of such highly efficient ssc/co3o4 composite cathodes in single-chamber fuel cells with direct hydrocarbon fuels operating at temperatures below 500 degrees c. (c) 2008 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | electrochemistry ; energy & fuels |
| 研究领域[WOS] | electrochemistry ; energy & fuels |
| 关键词[WOS] | oxygen reduction ; high-performance ; it-sofc ; electrolyte ; stability ; kinetics ; anode ; co2 |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000259906600018 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/141003]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Haizhou,Liu, Huanying,Cong, You,et al. Investigation of SM0.5Sr0.5CoO3-delta/Co3O4 composite cathode for intermediate-temperature solid oxide fuel cells[J]. journal of power sources,2008,185(1):129-135. |
| APA | Zhang, Haizhou,Liu, Huanying,Cong, You,&Yang, Weishen.(2008).Investigation of SM0.5Sr0.5CoO3-delta/Co3O4 composite cathode for intermediate-temperature solid oxide fuel cells.journal of power sources,185(1),129-135. |
| MLA | Zhang, Haizhou,et al."Investigation of SM0.5Sr0.5CoO3-delta/Co3O4 composite cathode for intermediate-temperature solid oxide fuel cells".journal of power sources 185.1(2008):129-135. |
入库方式： OAI收割
来源：大连化学物理研究所
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