Thermal decomposition kinetics of the synthetic complex Pb(1,4-BDC)center dot(DMF)(H2O)
文献类型:期刊论文
作者 | Zhang, J.1,2; Zeng, J. L.1,2; Liu, Y. Y.1; Sun, L. X.1,2; Xu, F.; You, W. S.3; Sawada, Y.4 |
刊名 | journal of thermal analysis and calorimetry
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出版日期 | 2008 |
卷号 | 91期号:1页码:189-193 |
关键词 | apparent activation energy kinetic model TG-DTG thermal decomposition |
英文摘要 | pb(1,4-bdc)center dot(dmf)(h2o) (1,4-bdc=1,4-benzenedicarboxylate; dmf=dimethylformamide) has been synthesized and investigated by elemental analysis, ftir spectroscopy, thermogravimetry (tg), derivative thermogravimetry (dtg). tg-dtg curves show that the thermal decomposition occurs in four stages and the corresponding apparent activation energies were calculated with the ozawa-flynn-wall (ofw) and the friedman methods. the most probable kinetic model function of the dehydration reaction of the compound has been estimated by the coats-redfern integral and the achar-bridly-sharp differential methods in this study. |
WOS标题词 | science & technology ; physical sciences |
类目[WOS] | chemistry, analytical ; chemistry, physical |
研究领域[WOS] | chemistry |
关键词[WOS] | metal-organic framework ; thermogravimetric data ; coordination polymers ; design |
收录类别 | SCI ; ISTP |
语种 | 英语 |
WOS记录号 | WOS:000252889200028 |
公开日期 | 2015-11-17 |
源URL | [http://159.226.238.44/handle/321008/141027] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Mat & Thermochem Lab, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China 3.Liaoning Normal Univ, Fac Chem & Chem Engn, Dalian 116029, Peoples R China 4.Tokyo Polytech Univ, Fac Engn, Dept Nanochem, Atsugi, Kanagawa 2430297, Japan |
推荐引用方式 GB/T 7714 | Zhang, J.,Zeng, J. L.,Liu, Y. Y.,et al. Thermal decomposition kinetics of the synthetic complex Pb(1,4-BDC)center dot(DMF)(H2O)[J]. journal of thermal analysis and calorimetry,2008,91(1):189-193. |
APA | Zhang, J..,Zeng, J. L..,Liu, Y. Y..,Sun, L. X..,Xu, F..,...&Sawada, Y..(2008).Thermal decomposition kinetics of the synthetic complex Pb(1,4-BDC)center dot(DMF)(H2O).journal of thermal analysis and calorimetry,91(1),189-193. |
MLA | Zhang, J.,et al."Thermal decomposition kinetics of the synthetic complex Pb(1,4-BDC)center dot(DMF)(H2O)".journal of thermal analysis and calorimetry 91.1(2008):189-193. |
入库方式: OAI收割
来源:大连化学物理研究所
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