Hydrogen production from ethanol over Ir/CeO2 catalysts: A comparative study of steam reforming, partial oxidation and oxidative steam reforming
文献类型：期刊论文
| 作者 | Cai, Weijie1; Wang, Fagen1; Zhan, Ensheng1; Van Veen, A. C.2; Mirodatos, Claude2; Shen, Wenjie1 |
| 刊名 | journal of catalysis
 |
| 出版日期 | 2008-07-01 |
| 卷号 | 257期号:1页码:96-107 |
| 关键词 | ethanol hydrogen Ir/CeO2 reaction pathway stability |
| 英文摘要 | steam reforming, partial oxidation, and oxidative steam reforming of ethanol over ir/ceo2 catalysts were studied to elucidate the reaction pathway and determine catalytic stability. temperature-programmed desorption and surface reaction revealed that ethoxy species were immediately formed on ethanol adsorption at room temperature, and were mainly further oxidized to acetate and carbonate species that finally decomposed into ch4/co and co2, respectively. under reaction conditions, acetalclehyde was the primary product below 673 k, which decomposed mainly to methane and carbon monoxide at higher temperatures, whereas methane reforming and the water-gas shift were the major reactions above 773 k. the ir/ceo2 catalyst demonstrated rather high stability for the reactions at 823 and 923 k with no apparent deactivation for 60 h on stream; the mean size of it particles was stable at around 2-3 nm, but the ceria particles sintered significantly from 6-8 to 14-27 nm. ceo2 likely prevented the highly dispersed it particles from sintering and inhibited coke deposition through strong ir-ceo2 interactions. (c) 2008 elsevier inc. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | fuel-cell applications ; temperature-programmed desorption ; biomass-derived ethanol ; noble-metal catalysts ; carbon-carbon bond ; ni-based catalysts ; situ ft-ir ; bio-ethanol ; h-2 production ; rh |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000257810500012 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/141084]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Univ Lyon 1, CNRS, IRCELYON, UMR 5256,Univ Lyon, F-69626 Villeurbanne, France |
| 推荐引用方式 GB/T 7714 | Cai, Weijie,Wang, Fagen,Zhan, Ensheng,et al. Hydrogen production from ethanol over Ir/CeO2 catalysts: A comparative study of steam reforming, partial oxidation and oxidative steam reforming[J]. journal of catalysis,2008,257(1):96-107. |
| APA | Cai, Weijie,Wang, Fagen,Zhan, Ensheng,Van Veen, A. C.,Mirodatos, Claude,&Shen, Wenjie.(2008).Hydrogen production from ethanol over Ir/CeO2 catalysts: A comparative study of steam reforming, partial oxidation and oxidative steam reforming.journal of catalysis,257(1),96-107. |
| MLA | Cai, Weijie,et al."Hydrogen production from ethanol over Ir/CeO2 catalysts: A comparative study of steam reforming, partial oxidation and oxidative steam reforming".journal of catalysis 257.1(2008):96-107. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。