"Ir-in-ceria": A highly selective catalyst for preferential CO oxidation
文献类型：期刊论文
| 作者 | Huang, Yanqiang1,2; Wang, Aiqin1; Li, Lin1; Wang, Xiaodong1; Su, Dangsheng3; Zhang, Tao1 |
| 刊名 | journal of catalysis
 |
| 出版日期 | 2008-04-25 |
| 卷号 | 255期号:2页码:144-152 |
| 关键词 | preferential CO oxidation iridium ceria selectivity Ir/CeO2 |
| 英文摘要 | an ir-in-ceria catalyst has been developed, in which most of the iridium particles are embedded in the ceria matrix through the redox reaction between ce3+ and ir4+, which occurred during co-precipitation (cp). this ir-cp catalyst exhibited high activity for preferential co oxidation under excess hydrogen conditions, and the selectivity to co2 remained nearly constant, at around 70%, with increasing reaction temperature. temperature-programmed reduction and in situ diffuse reflectance infrared spectroscopy techniques were used to explore the structure of the ir-cp catalyst and to correlate it with the catalytic performance. it was found that the ceo2 support was activated by iridium and formed on the surface the active sites for co oxidation. due to the absence of extensively exposed ir species on the ir-cp catalyst, h-2 oxidation occurring on the ir species and the ceria support at high temperatures was significantly suppressed, thus keeping the selectivity to co2 at a high level. (c) 2008 elsevier inc. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | water-gas-shift ; carbon-monoxide ; hydrogen prox ; pt/ceo2 catalyst ; supported catalysts ; iridium catalysts ; gold ; temperature ; platinum ; dioxide |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000255668200002 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/141117]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China 3.Max Planck Gesell, Fritz Haber Inst, D-14195 Berlin, Germany |
| 推荐引用方式 GB/T 7714 | Huang, Yanqiang,Wang, Aiqin,Li, Lin,et al. "Ir-in-ceria": A highly selective catalyst for preferential CO oxidation[J]. journal of catalysis,2008,255(2):144-152. |
| APA | Huang, Yanqiang,Wang, Aiqin,Li, Lin,Wang, Xiaodong,Su, Dangsheng,&Zhang, Tao.(2008)."Ir-in-ceria": A highly selective catalyst for preferential CO oxidation.journal of catalysis,255(2),144-152. |
| MLA | Huang, Yanqiang,et al.""Ir-in-ceria": A highly selective catalyst for preferential CO oxidation".journal of catalysis 255.2(2008):144-152. |
入库方式： OAI收割
来源：大连化学物理研究所
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