Selective hydrogenation of cinnamaldehyde to hydrocinnamaldehyde over SiO(2) supported nickel phosphide catalysts
文献类型：期刊论文
| 作者 | Wang, Hui1,2; Shu, Yuying1; Zheng, Mingyuan1; Zhang, Tao1 |
| 刊名 | catalysis letters
 |
| 出版日期 | 2008-08-01 |
| 卷号 | 124期号:3-4页码:219-225 |
| 关键词 | metal phosphide Ni(12)P(5) Ni(2)P cinnamaldehyde hydrogenation Pd/SiO(2) hydrocinnamaldehyde |
| 英文摘要 | a series of sio(2) supported transition metal (fe, co, ni, mo and w) phosphide catalysts were synthesized and tested for the selective hydrogenation of cinnamaldehyde (cma). among these tested catalysts, ni(12)p(5)/sio(2) and ni(2)p/sio(2) prepared with initial ni/p ratios of 2/1.3 and 1/1 exhibited high activity and selectivity for the conversion of cma to hydrocinnamaldehyde (hcma). the two nickel phosphide catalysts showed selectivity to hcma up to 90% at a conversion of 90%. the properties of the nickel phosphide catalysts were characterized by bet surface area determinations, x-ray powder diffraction (xrd) analysis, and transmission electron microscopy (tem). the influences of reaction temperature, hydrogen pressure, ni/p ratio, and reduction temperature were studied in detail. for comparison, pd/sio(2) catalyst was also used in this reaction, and the possible reasons for the different catalytic performances of the two kinds of catalysts are presented. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | transition-metal phosphides ; liquid-phase reactions ; cinnamyl alcohol ; amorphous alloy ; hydrotreating activity ; molybdenum phosphide ; platinum catalysts ; palladium catalyst ; cobalt catalysts ; silica |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000258528000009 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/141146]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Hui,Shu, Yuying,Zheng, Mingyuan,et al. Selective hydrogenation of cinnamaldehyde to hydrocinnamaldehyde over SiO(2) supported nickel phosphide catalysts[J]. catalysis letters,2008,124(3-4):219-225. |
| APA | Wang, Hui,Shu, Yuying,Zheng, Mingyuan,&Zhang, Tao.(2008).Selective hydrogenation of cinnamaldehyde to hydrocinnamaldehyde over SiO(2) supported nickel phosphide catalysts.catalysis letters,124(3-4),219-225. |
| MLA | Wang, Hui,et al."Selective hydrogenation of cinnamaldehyde to hydrocinnamaldehyde over SiO(2) supported nickel phosphide catalysts".catalysis letters 124.3-4(2008):219-225. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。