Aerobic Oxidation of Alcohols to Carbonyl Compounds Catalyzed by Fe(NO3)(3)/4-OH-TEMPO under Mild Conditions
文献类型：期刊论文
| 作者 | Wang Xinliang1,2; Liang Xinmiao1 |
| 刊名 | chinese journal of catalysis
 |
| 出版日期 | 2008-09-01 |
| 卷号 | 29期号:9页码:935-939 |
| 关键词 | alcohol selective oxidation air 4-hydroxy-2 ferric nitrate nonahydrate 2 6 6-tetramethyl-piperidyl-1-oxy |
| 英文摘要 | a fe(no3)(3)/4-oh-tempo catalyst system was developed using the inexpensive organocatalyst 4-hydroxy-2,2,6,6-tetramethyl-piperidyl-1-oxy (4-oh-tempo) and the co-catalyst fe(no3)(3) center dot 9h(2)o. the catalytic molecular-oxygen-driven oxidation of a broad range of primary and secondary alcohols, which may contain carbon-carbon double bond, n, o, and s heteroatoms, to the corresponding aldehydes and ketones was investigated. the results showed that reaction is highly selective to the desired products when carried out at room temperature in ambient atmosphere air. the mechanism for the catalytic aerobic oxidation of alcohols by fe (no3)(3)/4-oh-tempo was discussed. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | transition-metal-free ; selective oxidation ; highly efficient ; molecular-oxygen ; tempo ; organocatalyst ; aldehydes ; mediators |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000260196700019 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/141165]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang Xinliang,Liang Xinmiao. Aerobic Oxidation of Alcohols to Carbonyl Compounds Catalyzed by Fe(NO3)(3)/4-OH-TEMPO under Mild Conditions[J]. chinese journal of catalysis,2008,29(9):935-939. |
| APA | Wang Xinliang,&Liang Xinmiao.(2008).Aerobic Oxidation of Alcohols to Carbonyl Compounds Catalyzed by Fe(NO3)(3)/4-OH-TEMPO under Mild Conditions.chinese journal of catalysis,29(9),935-939. |
| MLA | Wang Xinliang,et al."Aerobic Oxidation of Alcohols to Carbonyl Compounds Catalyzed by Fe(NO3)(3)/4-OH-TEMPO under Mild Conditions".chinese journal of catalysis 29.9(2008):935-939. |
入库方式： OAI收割
来源：大连化学物理研究所
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