Effective heterogenization and catalytic use of active C(5)H(5)NiLX complex for the hydrosilylation
文献类型：期刊论文
| 作者 | Xu, Z.1,2; Lu, X. -H.1,2; Xia, Q. -H.1,2; Lou, Z. -W.1,2; Ye, C. -P.1,2; Liu, Z. -M.3 |
| 刊名 | catalysis communications
 |
| 出版日期 | 2008-04-20 |
| 卷号 | 9期号:8页码:1793-1798 |
| 关键词 | polystyrene beads immobilization heterogeneous solid nickel complex catalyst hydrosilylation |
| 英文摘要 | an effective route was first developed to heterogenize active c(5)h(5)nilx complex for the preparation of the solid catalyst (p) - ch(2)c(5)h(4)nipph(3)cl. the attachment of the nickel complex onto the polymer was carefully characterized by ir, solid diffuse reflectance uv - vis, (31)p cp masnmr spectra and icp-oes elemental analysis, which proved that the present route was relatively simple and effective for the immobilization of active centers, and that the materials used was considerably cheap. thus-prepared solid catalyst (p) - ch(2)c(5)h(4)nipph(3)cl showed high activity, selectivity and an excellent recyclability for the hydrosilylation of alkenes with trichlorosilane at mild conditions, outstandingly overcoming the problem of homogeneous system. this is a key success to provide a new methodology for heterogenizing active homogeneous components. (c) 2008 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | rhodium ; ruthenium ; olefins |
| 收录类别 | SCI ; CCR |
| 语种 | 英语 |
| WOS记录号 | WOS:000255381600023 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/141206]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Hubei Univ, Minist Educ, Key Lab Synth & Applicat Organ Funct Mol, Wuhan 430062, Peoples R China 2.Hubei Univ, Sch Chem & Chem Engn, Wuhan 430062, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, Grp 803, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xu, Z.,Lu, X. -H.,Xia, Q. -H.,et al. Effective heterogenization and catalytic use of active C(5)H(5)NiLX complex for the hydrosilylation[J]. catalysis communications,2008,9(8):1793-1798. |
| APA | Xu, Z.,Lu, X. -H.,Xia, Q. -H.,Lou, Z. -W.,Ye, C. -P.,&Liu, Z. -M..(2008).Effective heterogenization and catalytic use of active C(5)H(5)NiLX complex for the hydrosilylation.catalysis communications,9(8),1793-1798. |
| MLA | Xu, Z.,et al."Effective heterogenization and catalytic use of active C(5)H(5)NiLX complex for the hydrosilylation".catalysis communications 9.8(2008):1793-1798. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。