Direct observation of the active center for methane dehydroaromatization using an ultrahigh field Mo-95 NMR spectroscopy
文献类型:期刊论文
作者 | Zheng, Heng1; Ma, Ding1; Bao, Xinhe1; Hu, Jian Zhi2; Kwak, Ja Hun2; Wang, Yong2; Peden, Charles H. F.2 |
刊名 | journal of the american chemical society
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出版日期 | 2008-03-26 |
卷号 | 130期号:12页码:3722-+ |
英文摘要 | the use of an ultrahigh magnetic field spectrometer and mo-95 isotope enrichment facilitate the direct observation of the local structure of mo species on mo/zeolite catalysts by 95mo nmr. top trace: the experimental 95mo nmr spectrum of 6mo/hzsm-5. bottom traces: the simulated overall spectrum (orange), the spectral component corresponding to moo3 (purple), and the component corresponding to the exchanged mo species (green). the exchanged mo species proved to be the active center for the methane dehydroaromatization (mda) reaction. |
WOS标题词 | science & technology ; physical sciences |
类目[WOS] | chemistry, multidisciplinary |
研究领域[WOS] | chemistry |
关键词[WOS] | solid-state nmr ; zeolite catalysts ; hydrodesulfurization catalysts ; mo ; aromatization ; naphthalene ; conversion ; mo/h-zsm5 ; mo/hzsm-5 ; benzene |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000254173600009 |
公开日期 | 2015-11-17 |
源URL | [http://159.226.238.44/handle/321008/141209] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Pacific NW Natl Lab, Richland, WA 99352 USA |
推荐引用方式 GB/T 7714 | Zheng, Heng,Ma, Ding,Bao, Xinhe,et al. Direct observation of the active center for methane dehydroaromatization using an ultrahigh field Mo-95 NMR spectroscopy[J]. journal of the american chemical society,2008,130(12):3722-+. |
APA | Zheng, Heng.,Ma, Ding.,Bao, Xinhe.,Hu, Jian Zhi.,Kwak, Ja Hun.,...&Peden, Charles H. F..(2008).Direct observation of the active center for methane dehydroaromatization using an ultrahigh field Mo-95 NMR spectroscopy.journal of the american chemical society,130(12),3722-+. |
MLA | Zheng, Heng,et al."Direct observation of the active center for methane dehydroaromatization using an ultrahigh field Mo-95 NMR spectroscopy".journal of the american chemical society 130.12(2008):3722-+. |
入库方式: OAI收割
来源:大连化学物理研究所
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