High-performance liquid chromatographic evaluation of a coated cellulose tris(3,5-dimethylphenylcarbamate) chiral stationary phase having a small-pore silica support
文献类型：期刊论文
| 作者 | Liu, Yueqi; Zou, Hanfa |
| 刊名 | journal of chromatography a
 |
| 出版日期 | 2008-01-12 |
| 卷号 | 1178期号:1-2页码:118-125 |
| 关键词 | chiral stationary phase cellulose tris(3 small-pore silica enantiomeric separation HPLC 5-dimethylphenylcarbamate) |
| 英文摘要 | a two-step coating/precipitation synthetic procedure has been developed for the preparation of cellulose tris(3,5-dimethylphenylcarbamate) chiral stationary phase (csp) having a small-pore silica support. with this synthetic strategy, monodisperse, spherical csp particles can be produced without the need for a wasteful and time-consuming sieving process. the performance of the synthesized csp towards a variety of racemates was evaluated in the normal-phase hplc mode. hplc separation experiments revealed that the synthesized csp exhibited a chiral recognition ability fully comparable to the corresponding commercial columns prepared using conventional large-pore silica as the support. moreover, the synthesized csp was successfully applied to semipreparative enantioseparation of a new triazole antifungal agent. (c) 2007 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; life sciences & biomedicine ; physical sciences |
| 类目[WOS] | biochemical research methods ; chemistry, analytical |
| 研究领域[WOS] | biochemistry & molecular biology ; chemistry |
| 关键词[WOS] | direct optical resolution ; amylose ; hplc ; enantiomers ; gel ; 3,5-dimethylphenylcarbamate ; separations ; derivatives ; drugs ; enantioselectivity |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000252477400014 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/141239]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, Natl Chromatog Res & Anal Ctr, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Yueqi,Zou, Hanfa. High-performance liquid chromatographic evaluation of a coated cellulose tris(3,5-dimethylphenylcarbamate) chiral stationary phase having a small-pore silica support[J]. journal of chromatography a,2008,1178(1-2):118-125. |
| APA | Liu, Yueqi,&Zou, Hanfa.(2008).High-performance liquid chromatographic evaluation of a coated cellulose tris(3,5-dimethylphenylcarbamate) chiral stationary phase having a small-pore silica support.journal of chromatography a,1178(1-2),118-125. |
| MLA | Liu, Yueqi,et al."High-performance liquid chromatographic evaluation of a coated cellulose tris(3,5-dimethylphenylcarbamate) chiral stationary phase having a small-pore silica support".journal of chromatography a 1178.1-2(2008):118-125. |
入库方式： OAI收割
来源：大连化学物理研究所
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