Co/MgO catalysts for hydrogenolysis of glycerol to 1, 2-propanediol
文献类型：期刊论文
| 作者 | Guo, Xiaohui; Li, Yong; Shi, Ruijuan; Liu, Qiying; Zhan, Ensheng; Shen, Wenjie |
| 刊名 | applied catalysis a-general
 |
| 出版日期 | 2009-12-15 |
| 卷号 | 371期号:1-2页码:108-113 |
| 关键词 | Glycerol Hydrogenolysis 1 Co/MgO 2-Propanediol |
| 英文摘要 | hydrogenolysis of glycerol to 1, 2-propanediol was investigated on bi-functional co/mgo catalysts where the interaction between cobalt species and mgo was adjusted by varying the temperature of calcination. higher temperature treatment not only enhanced the interaction between co(3)o(4) and mgo, but also promoted the formation of mgco(2)o(4) spinel and mg-co-o solid solution. although the reducibility of cobalt oxides was greatly decreased in the co(3)o(4)/mgo precursor, this strong interaction prevented the aggregation of co particles in the resulting co/mgo catalyst under the harsh reaction conditions, giving a much higher activity and stability. results revealed that mgo was hydrated to mg(oh)(2) during the course of reaction and that the sizes of mg(oh)(2) and co particles increased considerably, especially during the initial stage of the reaction. (c) 2009 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; life sciences & biomedicine |
| 类目[WOS] | chemistry, physical ; environmental sciences |
| 研究领域[WOS] | chemistry ; environmental sciences & ecology |
| 关键词[WOS] | ion-exchange-resin ; cu-zno catalysts ; selective hydrogenolysis ; propylene-glycol ; oxidation ; oxide ; temperature ; propanediol ; acrolein ; co/sio2 |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000272765000015 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/141240]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Guo, Xiaohui,Li, Yong,Shi, Ruijuan,et al. Co/MgO catalysts for hydrogenolysis of glycerol to 1, 2-propanediol[J]. applied catalysis a-general,2009,371(1-2):108-113. |
| APA | Guo, Xiaohui,Li, Yong,Shi, Ruijuan,Liu, Qiying,Zhan, Ensheng,&Shen, Wenjie.(2009).Co/MgO catalysts for hydrogenolysis of glycerol to 1, 2-propanediol.applied catalysis a-general,371(1-2),108-113. |
| MLA | Guo, Xiaohui,et al."Co/MgO catalysts for hydrogenolysis of glycerol to 1, 2-propanediol".applied catalysis a-general 371.1-2(2009):108-113. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。