In-situ C-13 MAS NMR investigation of solvent effect on the formation of phenylacetaldehyde over TS-1 zeolite
文献类型：期刊论文
| 作者 | Zhuang, Jianqin1,2; Han, Xiuwen1; Bao, Xinhe1; Mueller, Ulrich3 |
| 刊名 | journal of catalysis
 |
| 出版日期 | 2009-10-25 |
| 卷号 | 267期号:2页码:177-180 |
| 关键词 | Solvent effect In-situ NMR Titanium molecular sieve Styrene oxidation Phenylacetaldehyde |
| 英文摘要 | in-situ c-13 mas nmr techniques were used to investigate the effects of different solvent systems on the formation of phenylacetalclehyde (padh) over ts-1 zeolite, protic solvents such as water and methanol provide acidic centers during the reaction. these acidic species catalyzed the transformation of the intermediates to padh. whereas in the presence of aprotic solvents such as acetone, the precursor of padh remains stable on the framework of ts-1 and accordingly there is no padh formation. (c) 2009 elsevier inc. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | hydrogen-peroxide ; titanium silicalite ; epoxidation reaction ; oxidation catalysts ; oxidizing-agent ; styrene ; oxide ; h2o2 |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000271112500010 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/141242]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.CUNY Coll Staten Isl, Dept Chem, Staten Isl, NY 10314 USA 3.BASF AG, GCC Z M301, D-67056 Ludwigshafen, Germany |
| 推荐引用方式 GB/T 7714 | Zhuang, Jianqin,Han, Xiuwen,Bao, Xinhe,et al. In-situ C-13 MAS NMR investigation of solvent effect on the formation of phenylacetaldehyde over TS-1 zeolite[J]. journal of catalysis,2009,267(2):177-180. |
| APA | Zhuang, Jianqin,Han, Xiuwen,Bao, Xinhe,&Mueller, Ulrich.(2009).In-situ C-13 MAS NMR investigation of solvent effect on the formation of phenylacetaldehyde over TS-1 zeolite.journal of catalysis,267(2),177-180. |
| MLA | Zhuang, Jianqin,et al."In-situ C-13 MAS NMR investigation of solvent effect on the formation of phenylacetaldehyde over TS-1 zeolite".journal of catalysis 267.2(2009):177-180. |
入库方式： OAI收割
来源：大连化学物理研究所
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