Highly Enantioselective Iridium-Catalyzed Hydrogenation of 2-Benzylquinolines and 2-Functionalized and 2,3-Disubstituted Quinolines
文献类型：期刊论文
| 作者 | Wang, Da-Wei1; Wang, Xiao-Bing1; Wang, Duo-Sheng1; Lu, Sheng-Mei1; Zhou, Yong-Gui1,2; Li, Yu-Xue2 |
| 刊名 | journal of organic chemistry
 |
| 出版日期 | 2009-04-03 |
| 卷号 | 74期号:7页码:2780-2787 |
| 英文摘要 | the enantioselective hydrogenation of 2-benzylquinolines and 2-functionalized and 2,3-disubstituted quinolines was developed by using the [ir(cod)cl]2/bisphosphine/i(2) system with up to 96% ee. moreover, mechanistic studies revealed the hydrogenation mechanism of quinoline involves a 1,4-hydride addition, isomerization, and 1,2-hydride addition, and the catalytic active species may be a ir(iii) complex with chloride and iodide. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, organic |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | asymmetric transfer hydrogenation ; n-iminopyridinium ylides ; ir-f-binaphane ; heteroaromatic-compounds ; homogeneous hydrogenation ; hantzsch esters ; complexes ; ligands ; derivatives ; indoles |
| 收录类别 | SCI ; IC ; CCR |
| 语种 | 英语 |
| WOS记录号 | WOS:000264627400018 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/141246]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Da-Wei,Wang, Xiao-Bing,Wang, Duo-Sheng,et al. Highly Enantioselective Iridium-Catalyzed Hydrogenation of 2-Benzylquinolines and 2-Functionalized and 2,3-Disubstituted Quinolines[J]. journal of organic chemistry,2009,74(7):2780-2787. |
| APA | Wang, Da-Wei,Wang, Xiao-Bing,Wang, Duo-Sheng,Lu, Sheng-Mei,Zhou, Yong-Gui,&Li, Yu-Xue.(2009).Highly Enantioselective Iridium-Catalyzed Hydrogenation of 2-Benzylquinolines and 2-Functionalized and 2,3-Disubstituted Quinolines.journal of organic chemistry,74(7),2780-2787. |
| MLA | Wang, Da-Wei,et al."Highly Enantioselective Iridium-Catalyzed Hydrogenation of 2-Benzylquinolines and 2-Functionalized and 2,3-Disubstituted Quinolines".journal of organic chemistry 74.7(2009):2780-2787. |
入库方式： OAI收割
来源：大连化学物理研究所
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