High Resolution Crossed Beams Scattering Study of the F plus HD -> DF plus H Reaction
文献类型:期刊论文
作者 | Wang, Xing-an1; Che, Li1; Ren, Ze-feng1; Qiu, Ming-hui1,2; Dai, Dong-xu1; Wang, Xiu-yan1; Yang, Xue-ming1 |
刊名 | chinese journal of chemical physics
![]() |
出版日期 | 2009-12-27 |
卷号 | 22期号:6页码:551-555 |
关键词 | F plus HD -> DF plus H Crossed beam Rydberg tagging Backward scattering |
英文摘要 | crossed beams scattering study was carried out on the f+hd -> df+h reaction using high-resolution h-atom rydberg tagging time-of-flight technique. vibrational state-resolved differential cross sections were measured, with partial rotational state resolution, at eight collision energies in the range of 2.51-5.60 kj/mol. experimental results indicated that the product angular distributions are predominantly backward scattered. as the collision energy increases, the backward scattered peak becomes broader gradually. dependence of product vibration branching ratios on the collision energy was also determined. the experimental results show that the df products are highly inverted in the vibrational state distribution and the df (v'=3) product is the most populated state. furthermore, the df (v'=1) product has also been observed at collision energy above 3.97 kj/mol. |
WOS标题词 | science & technology ; physical sciences |
类目[WOS] | physics, atomic, molecular & chemical |
研究领域[WOS] | physics |
关键词[WOS] | potential-energy surface ; f+hd reaction ; molecular-beam ; rate constants ; atom reaction ; resonance ; sections ; dynamics |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000273466600001 |
公开日期 | 2015-11-17 |
源URL | [http://159.226.238.44/handle/321008/141249] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China 2.Dalian Jiaotong Univ, Dept Phys, Dalian 116028, Peoples R China |
推荐引用方式 GB/T 7714 | Wang, Xing-an,Che, Li,Ren, Ze-feng,et al. High Resolution Crossed Beams Scattering Study of the F plus HD -> DF plus H Reaction[J]. chinese journal of chemical physics,2009,22(6):551-555. |
APA | Wang, Xing-an.,Che, Li.,Ren, Ze-feng.,Qiu, Ming-hui.,Dai, Dong-xu.,...&Yang, Xue-ming.(2009).High Resolution Crossed Beams Scattering Study of the F plus HD -> DF plus H Reaction.chinese journal of chemical physics,22(6),551-555. |
MLA | Wang, Xing-an,et al."High Resolution Crossed Beams Scattering Study of the F plus HD -> DF plus H Reaction".chinese journal of chemical physics 22.6(2009):551-555. |
入库方式: OAI收割
来源:大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。