NUMERICAL MODELING OF THE VIBRATIONAL POPULATION DISTRIBUTION OF POLYATOMIC MOLECULES EXCITED BY IR LASERS
文献类型：期刊论文
| 作者 | Wang Zhongcheng1; Chen Xirong1; Li Zhongyuan2; Li Mu2 |
| 刊名 | acta physico-chimica sinica
 |
| 出版日期 | 1987 |
| 卷号 | 3期号:2页码:185-191 |
| 英文摘要 | a computing model is presented for the calculation of the transient population distribution of polyatomic molecules excited by an ir laser pulse, sf8 has been used as an example. this model allows the calculation of the vibrational energy distribution from the observe ir fluorescence or adsorption spectrum, and vice versa. the thermal vibrational distribution calculated by this model the measured spectrum of sf6 at 300 k is in good agreement with the boltzmann distribution (table 1). the present model has a few advantages over an earlier study((1)), such as higher precision of computation, accurate generation of the vibrational transition matrix and being capable of calculating the transient vibrational population distribution at any instant after laser excitation. using the model as rotationally resolved spectrum of sf6 at 20k has been obtained for the first time. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000207569200013 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/141250]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Acad Sinica, Dalian Inst Chem Phys, Dalian, Peoples R China 2.Acad Sinica, Shenyong Inst Comp Technol, Taipei, Taiwan |
| 推荐引用方式 GB/T 7714 | Wang Zhongcheng,Chen Xirong,Li Zhongyuan,et al. NUMERICAL MODELING OF THE VIBRATIONAL POPULATION DISTRIBUTION OF POLYATOMIC MOLECULES EXCITED BY IR LASERS[J]. acta physico-chimica sinica,1987,3(2):185-191. |
| APA | Wang Zhongcheng,Chen Xirong,Li Zhongyuan,&Li Mu.(1987).NUMERICAL MODELING OF THE VIBRATIONAL POPULATION DISTRIBUTION OF POLYATOMIC MOLECULES EXCITED BY IR LASERS.acta physico-chimica sinica,3(2),185-191. |
| MLA | Wang Zhongcheng,et al."NUMERICAL MODELING OF THE VIBRATIONAL POPULATION DISTRIBUTION OF POLYATOMIC MOLECULES EXCITED BY IR LASERS".acta physico-chimica sinica 3.2(1987):185-191. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。