Direct Oxidation of Benzene to Phenol by Dioxygen over Nano-vanadium Oxide
文献类型：期刊论文
| 作者 | Gao Xiaohan2; Lue Xuechuan2; Xu Jie1 |
| 刊名 | chinese journal of chemistry
 |
| 出版日期 | 2009-11-01 |
| 卷号 | 27期号:11页码:2155-2158 |
| 关键词 | oxidation benzene phenol nano-vanadium oxide nanorod |
| 英文摘要 | reducing regents, such as ascorbic acid, are needed for vanadium-containing catalysts to catalyze the direct oxidation of benzene to phenol by dioxygen. quadrivalent vanadium species, reduced from quinquevalent vanadium species, can activate dioxy.-en to produce active oxygen species. which is important for the reaction the key step is to prepare more v-44-containing catalysts here, vox-c16-a was prepared in in acidic medium to produce more v4+ species. the results of xps and xrd studies confirmed that the vanadium species in vox-c-16-(a) was mainly v4+ ions the results of xrd and electron diffraction patterns revealed that vox-c-16-a consisted of tetragonal vo2 and monoclinic vo2, morphology observations display that the vox-c-16-(a) is made of nanorod. investigations into the performances of the catalysts showed that vox-c-16-(a) was reusable, producing a 1.9% conversion of benzene without reducing agent |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, multidisciplinary |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | liquid-phase oxidation ; hydrogen-peroxide ; molecular-oxygen ; acetic-acid ; catalysts ; hydroxylation ; spectroscopy ; nanotubes ; polyoxovanadates ; zeolites |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000272761600007 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/141266]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China 2.Liaoning Shihua Univ, Sch Chem & Mat Sci, Fushun 113001, Liaoning, Peoples R China |
| 推荐引用方式 GB/T 7714 | Gao Xiaohan,Lue Xuechuan,Xu Jie. Direct Oxidation of Benzene to Phenol by Dioxygen over Nano-vanadium Oxide[J]. chinese journal of chemistry,2009,27(11):2155-2158. |
| APA | Gao Xiaohan,Lue Xuechuan,&Xu Jie.(2009).Direct Oxidation of Benzene to Phenol by Dioxygen over Nano-vanadium Oxide.chinese journal of chemistry,27(11),2155-2158. |
| MLA | Gao Xiaohan,et al."Direct Oxidation of Benzene to Phenol by Dioxygen over Nano-vanadium Oxide".chinese journal of chemistry 27.11(2009):2155-2158. |
入库方式： OAI收割
来源：大连化学物理研究所
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