Effect of La2O3 doping on syntheses of C-1-C-18 mixed linear alpha-alcohols from syngas over the Co/AC catalysts
文献类型：期刊论文
| 作者 | Jiao, Guiping1,3; Ding, Yunjie1,2; Zhu, Hejun1; Li, Xianming1,3; Li, Jingwei1,3; Lin, Ronghe1,3; Dong, Wenda1,3; Gong, Leifeng1,3; Pei, Yanpeng1,3; Lu, Yuan1 |
| 刊名 | applied catalysis a-general
 |
| 出版日期 | 2009-07-31 |
| 卷号 | 364期号:1-2页码:137-142 |
| 关键词 | Mixed linear alpha-alcohols La doping Fischer-Tropsch synthesis Co-xLa/AC catalysts Co2C species |
| 英文摘要 | activated carbon-supported la-promoted co catalysts with different la dopings (15co-xla/ac) were prepared by the co-impregnation method and investigated by means of co hydrogenation, xrd, tpr-ms, co adsorption and tpsr-ms techniques. the results showed that mixed linear alpha-alcohols (c-1-c-18) can be directly synthesized from syngas over the la-doped 15co/ac catalysts under mild conditions and that the selectivity towards alcohols was improved by doping la into the 15co/ac catalysts. it was found that the reducibility of the 15co-xla/ac catalyst decreased and the co dispersion improved due to the strong interaction between co and la2o3 species. la2o3 can promote the formation of cobalt carbides (co2c) which are postulated to play an important role in the syntheses of the mixed linear alpha-alcohols. on the other hand, high co dispersion and an appropriate ratio of co2+/co-0 can enhance the activity of co hydrogenation. (c) 2009 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; life sciences & biomedicine |
| 类目[WOS] | chemistry, physical ; environmental sciences |
| 研究领域[WOS] | chemistry ; environmental sciences & ecology |
| 关键词[WOS] | supported cobalt catalysts ; fischer-tropsch catalysts ; carbon-monoxide ; hydrogenation ; lanthanum ; dioxide ; oxide |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000268512500019 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/141279]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 3.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jiao, Guiping,Ding, Yunjie,Zhu, Hejun,et al. Effect of La2O3 doping on syntheses of C-1-C-18 mixed linear alpha-alcohols from syngas over the Co/AC catalysts[J]. applied catalysis a-general,2009,364(1-2):137-142. |
| APA | Jiao, Guiping.,Ding, Yunjie.,Zhu, Hejun.,Li, Xianming.,Li, Jingwei.,...&Lu, Yuan.(2009).Effect of La2O3 doping on syntheses of C-1-C-18 mixed linear alpha-alcohols from syngas over the Co/AC catalysts.applied catalysis a-general,364(1-2),137-142. |
| MLA | Jiao, Guiping,et al."Effect of La2O3 doping on syntheses of C-1-C-18 mixed linear alpha-alcohols from syngas over the Co/AC catalysts".applied catalysis a-general 364.1-2(2009):137-142. |
入库方式： OAI收割
来源：大连化学物理研究所
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