Ambient temperature hydrogen desorption from LiAlH4-LiNH2 mediated by HMPA
文献类型：期刊论文
| 作者 | Zheng, Xueli1,2; Xu, Weiliang3; Xiong, Zhitao1; Chua, Yongshen3; Wu, Guotao1; Qin, Song2; Chen, Hua2; Chen, Ping1 |
| 刊名 | journal of materials chemistry
 |
| 出版日期 | 2009 |
| 卷号 | 19期号:44页码:8426-8431 |
| 英文摘要 | by adding a small amount of hmpa approximately 2.5 equivalent or ca. 8.1 wt% h-2 can be released from the lialh4-linh2 mixture at ambient temperature, which is similar to 370 degrees c lower than the corresponding solid-state dehydrogenation. nmr characterizations reveal the formation of intermediates, such as [alh] and [aln] species, during the dehydrogenation. linh2 induces the enrichment of [alh] species in the liquid phase which further reacts with linh2 to produce h-2, li2nh and al. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, physical ; materials science, multidisciplinary |
| 研究领域[WOS] | chemistry ; materials science |
| 关键词[WOS] | n-h system ; thermal-decomposition ; complex hydrides ; chemical-reaction ; storage materials ; ammonia-borane ; metal-hydrides ; lithium ; lib0.33n0.67h2.67 ; dehydrogenation |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000271744600022 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/141283]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Sichuan Univ, Key Lab Green Chem & Technol, Minist Educ, Inst Homogeneous Catalysis, Chengdu 610064, Peoples R China 3.Natl Univ Singapore, Dept Chem, Fac Sci, Singapore 117543, Singapore |
| 推荐引用方式 GB/T 7714 | Zheng, Xueli,Xu, Weiliang,Xiong, Zhitao,et al. Ambient temperature hydrogen desorption from LiAlH4-LiNH2 mediated by HMPA[J]. journal of materials chemistry,2009,19(44):8426-8431. |
| APA | Zheng, Xueli.,Xu, Weiliang.,Xiong, Zhitao.,Chua, Yongshen.,Wu, Guotao.,...&Chen, Ping.(2009).Ambient temperature hydrogen desorption from LiAlH4-LiNH2 mediated by HMPA.journal of materials chemistry,19(44),8426-8431. |
| MLA | Zheng, Xueli,et al."Ambient temperature hydrogen desorption from LiAlH4-LiNH2 mediated by HMPA".journal of materials chemistry 19.44(2009):8426-8431. |
入库方式： OAI收割
来源：大连化学物理研究所
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