Time-Resolved FTIR Study on the Reaction of CHCl2 with NO2
文献类型：期刊论文
| 作者 | Liu, Kun-hui; Yang, Chun-fan; Wang, Huan; Wu, Wei-qiang; Su, Hong-mei |
| 刊名 | chinese journal of chemical physics
 |
| 出版日期 | 2009-04-01 |
| 卷号 | 22期号:2页码:134-138 |
| 关键词 | TR-FTIR Dichloromethyl NO2 Reaction product channel |
| 英文摘要 | the environmentally important free radical reaction of chlorinated methyl chcl2 with no2 was investigated by step-scan time-resolved ftir (tr-ftir) emission spectroscopy. vibrationally excited products of chclo, no, co, and hcl are observed in the high-resolution ir emission spectra and three possible reaction channels are therefore elucidated. in particular, the product co is newly detected and the product hcl is identified explicitly as a yield from the chcl2+no2 reaction, taking advantage of the sensitive detection of hcl and co with tr-ftir. these results are of particular interests to understand the related realistic chemical processes including atmospheric photochemistry, biofuel combustion, waste destruction, and smoking fire. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | physics, atomic, molecular & chemical |
| 研究领域[WOS] | physics |
| 关键词[WOS] | radical-molecule reaction ; diode-laser ; kinetics ; cl ; photodissociation ; spectroscopy ; temperature ; chemistry ; mechanism ; ch2brcl |
| 收录类别 | SCI ; ISTP |
| 语种 | 英语 |
| WOS记录号 | WOS:000265896000006 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/141296]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, State Key Lab Mol React Dynam, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Kun-hui,Yang, Chun-fan,Wang, Huan,et al. Time-Resolved FTIR Study on the Reaction of CHCl2 with NO2[J]. chinese journal of chemical physics,2009,22(2):134-138. |
| APA | Liu, Kun-hui,Yang, Chun-fan,Wang, Huan,Wu, Wei-qiang,&Su, Hong-mei.(2009).Time-Resolved FTIR Study on the Reaction of CHCl2 with NO2.chinese journal of chemical physics,22(2),134-138. |
| MLA | Liu, Kun-hui,et al."Time-Resolved FTIR Study on the Reaction of CHCl2 with NO2".chinese journal of chemical physics 22.2(2009):134-138. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。