Thermodynamic Study on Complex of Terbium with Glycine Tb(Gly)(2)Cl-3 center dot 3H(2)O
文献类型：期刊论文
| 作者 | Liu Beiping3; Tan Zhicheng1,2; Zhang Jingnan1,2; Lue Xuechuan4; Zhang Dashun3; Chen Zhengan3 |
| 刊名 | chinese journal of chemistry
 |
| 出版日期 | 2009-07-01 |
| 卷号 | 27期号:7页码:1244-1248 |
| 关键词 | Tb(Gly)(2)Cl-3 center dot 3H(2)O heat capacity standard molar enthalpy IR spectra TG-DTG analysis |
| 英文摘要 | a terbium complex with glycine tb(gly)(2)cl-3 center dot 3h(2)o was synthesized and its ir spectrum was determined. the heat capacity of the complex was measured with a high-precision automatic adiabatic calorimeter over the temperature range from 81 to 378 k. from 170 to 247 k, two solid-solid phase transitions occurred at 186.054 and 244.063 k, respectively. thermal decomposition of the complex was studied by thermogravimetric (tg) techniques and a possible mechanism for the decomposition was suggested. by isoperibol solution-reaction calorimetry, the standard molar enthalpy of formation of tb(gly)(2)cl-3 center dot 3h(2)o was derived to be -(3109.5 +/- 3.1) kj.mol(-1). |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, multidisciplinary |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | heat-capacity measurements ; adiabatic calorimeter ; small samples ; acid |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000268625200006 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/141299]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, China Ion Liquid Lab, Dalian 116023, Liaoning, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Thermochem Lab, Dalian 116023, Liaoning, Peoples R China 3.Hunan Univ Arts & Sci, Dept Chem, Changde 415000, Hunan, Peoples R China 4.Shihua Univ, Sch Chem & Mat Sci, Fushun 113001, Liaoning, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu Beiping,Tan Zhicheng,Zhang Jingnan,et al. Thermodynamic Study on Complex of Terbium with Glycine Tb(Gly)(2)Cl-3 center dot 3H(2)O[J]. chinese journal of chemistry,2009,27(7):1244-1248. |
| APA | Liu Beiping,Tan Zhicheng,Zhang Jingnan,Lue Xuechuan,Zhang Dashun,&Chen Zhengan.(2009).Thermodynamic Study on Complex of Terbium with Glycine Tb(Gly)(2)Cl-3 center dot 3H(2)O.chinese journal of chemistry,27(7),1244-1248. |
| MLA | Liu Beiping,et al."Thermodynamic Study on Complex of Terbium with Glycine Tb(Gly)(2)Cl-3 center dot 3H(2)O".chinese journal of chemistry 27.7(2009):1244-1248. |
入库方式： OAI收割
来源：大连化学物理研究所
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