中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
In situ formation of HRh(CO)(2)(PPh3)(2) active species on the surface of a SBA-15 supported heterogeneous catalyst and the effect of support pore size on the hydroformylation of propene

文献类型:期刊论文

作者Yan, Li1; Ding, Yun J.1,2; Lin, Li W.1,2; Zhu, He J.1; Yin, Hong M.1; Li, Xian M.1; Lu, Yuan1
刊名journal of molecular catalysis a-chemical
出版日期2009-03-02
卷号300期号:1-2页码:116-120
关键词Triphenyl phosphine Rh SBA-15 Hydroformylation Propene
英文摘要a method of in situ formation of hrh(co)(2)(pph3)(2) active species on the surface of heterogeneous rh/sba-15 catalyst has been developed and confirmed in this work. the amount of active species formed inside the pores can be controlled by the support pore size. this class of pph3-rh/sba-15 catalyst has been employed in propene hydroformylation to be highly active, selective, stable, easily workable and recyclable. using tem, solid-state (31)p mas nmr, and in situ ft-ir, hrh(co)(2)(pph3)(2) active species can be characterized. (c) 2008 elsevier b.v. all rights reserved.
WOS标题词science & technology ; physical sciences
类目[WOS]chemistry, physical
研究领域[WOS]chemistry
关键词[WOS]fixed-bed hydroformylation ; homogeneous catalysis ; rhodium ; ligand ; precursors ; silica
收录类别SCI
语种英语
WOS记录号WOS:000264013400017
公开日期2015-11-17
源URL[http://159.226.238.44/handle/321008/141324]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Lab Appl Catalysis, Dalian 116023, Liaoning, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China
推荐引用方式
GB/T 7714
Yan, Li,Ding, Yun J.,Lin, Li W.,et al. In situ formation of HRh(CO)(2)(PPh3)(2) active species on the surface of a SBA-15 supported heterogeneous catalyst and the effect of support pore size on the hydroformylation of propene[J]. journal of molecular catalysis a-chemical,2009,300(1-2):116-120.
APA Yan, Li.,Ding, Yun J..,Lin, Li W..,Zhu, He J..,Yin, Hong M..,...&Lu, Yuan.(2009).In situ formation of HRh(CO)(2)(PPh3)(2) active species on the surface of a SBA-15 supported heterogeneous catalyst and the effect of support pore size on the hydroformylation of propene.journal of molecular catalysis a-chemical,300(1-2),116-120.
MLA Yan, Li,et al."In situ formation of HRh(CO)(2)(PPh3)(2) active species on the surface of a SBA-15 supported heterogeneous catalyst and the effect of support pore size on the hydroformylation of propene".journal of molecular catalysis a-chemical 300.1-2(2009):116-120.

入库方式: OAI收割

来源:大连化学物理研究所

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