In situ formation of HRh(CO)(2)(PPh3)(2) active species on the surface of a SBA-15 supported heterogeneous catalyst and the effect of support pore size on the hydroformylation of propene
文献类型：期刊论文
| 作者 | Yan, Li1; Ding, Yun J.1,2; Lin, Li W.1,2; Zhu, He J.1; Yin, Hong M.1; Li, Xian M.1; Lu, Yuan1 |
| 刊名 | journal of molecular catalysis a-chemical
 |
| 出版日期 | 2009-03-02 |
| 卷号 | 300期号:1-2页码:116-120 |
| 关键词 | Triphenyl phosphine Rh SBA-15 Hydroformylation Propene |
| 英文摘要 | a method of in situ formation of hrh(co)(2)(pph3)(2) active species on the surface of heterogeneous rh/sba-15 catalyst has been developed and confirmed in this work. the amount of active species formed inside the pores can be controlled by the support pore size. this class of pph3-rh/sba-15 catalyst has been employed in propene hydroformylation to be highly active, selective, stable, easily workable and recyclable. using tem, solid-state (31)p mas nmr, and in situ ft-ir, hrh(co)(2)(pph3)(2) active species can be characterized. (c) 2008 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | fixed-bed hydroformylation ; homogeneous catalysis ; rhodium ; ligand ; precursors ; silica |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000264013400017 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/141324]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Lab Appl Catalysis, Dalian 116023, Liaoning, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yan, Li,Ding, Yun J.,Lin, Li W.,et al. In situ formation of HRh(CO)(2)(PPh3)(2) active species on the surface of a SBA-15 supported heterogeneous catalyst and the effect of support pore size on the hydroformylation of propene[J]. journal of molecular catalysis a-chemical,2009,300(1-2):116-120. |
| APA | Yan, Li.,Ding, Yun J..,Lin, Li W..,Zhu, He J..,Yin, Hong M..,...&Lu, Yuan.(2009).In situ formation of HRh(CO)(2)(PPh3)(2) active species on the surface of a SBA-15 supported heterogeneous catalyst and the effect of support pore size on the hydroformylation of propene.journal of molecular catalysis a-chemical,300(1-2),116-120. |
| MLA | Yan, Li,et al."In situ formation of HRh(CO)(2)(PPh3)(2) active species on the surface of a SBA-15 supported heterogeneous catalyst and the effect of support pore size on the hydroformylation of propene".journal of molecular catalysis a-chemical 300.1-2(2009):116-120. |
入库方式： OAI收割
来源：大连化学物理研究所
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