Synthesis, characterization, and thermochemistry of the solid state coordination compound Zn(Nic)(2) center dot H(2)O(s) (Nic = nicotinic acid)
文献类型：期刊论文
| 作者 | Di, You-Ying1; Hong, Yuan-Ping1; Kong, Yu-Xia1; Yang, Wei-Wei1; Tan, Zhi-Cheng2 |
| 刊名 | journal of chemical thermodynamics
 |
| 出版日期 | 2009 |
| 卷号 | 41期号:1页码:80-83 |
| 关键词 | Zn(Nic)(2)center dot H(2)O(s) Solid phase reaction Isoperibol solution-reaction calorimetry Standard molar enthalpy of dissolution Standard molar enthalpy of formation |
| 英文摘要 | a novel compound, viz. zinc nicotinate monohydrate, was synthesized by the method of room temperature solid phase synthesis. the techniques of ft-ir chemical and elemental analyses and x-ray powder diffraction were applied to characterise the structure and composition of the complex. in accordance with hess' law, a thermochemical cycle was designed and the enthalpy change of the solid phase reaction of nicotinic acid with hydrated zinc acetate was determined to be delta(r)h(m)(o) = (46.71 +/- 0.21) kj . mol(-1) by use of an isoperibol solution-reaction calorimeter. the standard molar enthalpy of formation of the title complex zn(nic)(2) . h(2)o(s) was calculated as -(1062.3 +/- 2.0) kj . mol(-1) by use of the enthalpies of dissolution and other auxiliary thermodynamic data. (c) 2008 elsevier ltd. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | thermodynamics ; chemistry, physical |
| 研究领域[WOS] | thermodynamics ; chemistry |
| 关键词[WOS] | enthalpies |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000262195600014 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/141363]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Liaocheng Univ, Coll Chem & Chem Engn, Liaocheng 252059, Shandong, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Thermochem Lab, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Di, You-Ying,Hong, Yuan-Ping,Kong, Yu-Xia,et al. Synthesis, characterization, and thermochemistry of the solid state coordination compound Zn(Nic)(2) center dot H(2)O(s) (Nic = nicotinic acid)[J]. journal of chemical thermodynamics,2009,41(1):80-83. |
| APA | Di, You-Ying,Hong, Yuan-Ping,Kong, Yu-Xia,Yang, Wei-Wei,&Tan, Zhi-Cheng.(2009).Synthesis, characterization, and thermochemistry of the solid state coordination compound Zn(Nic)(2) center dot H(2)O(s) (Nic = nicotinic acid).journal of chemical thermodynamics,41(1),80-83. |
| MLA | Di, You-Ying,et al."Synthesis, characterization, and thermochemistry of the solid state coordination compound Zn(Nic)(2) center dot H(2)O(s) (Nic = nicotinic acid)".journal of chemical thermodynamics 41.1(2009):80-83. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。