Correlation between catalytic selectivity and oxygen storage capacity in autothermal reforming of methane over Rh/Ce0.45Zr0.45RE0.1 catalysts (RE = La, Pr, Nd, Sm, Eu, Gd, Tb)
文献类型：期刊论文
| 作者 | Cao, Lei1,2; Ni, Changjun1; Yuan, Zhongshan1; Wang, Shudong1 |
| 刊名 | catalysis communications
 |
| 出版日期 | 2009-03-30 |
| 卷号 | 10期号:8页码:1192-1195 |
| 关键词 | Autothermal reforming Methane CeO2-ZrO2 Rare-earth |
| 英文摘要 | trivalent rare-earth (re = la, pr, nd, sm, eu, gd, tb)-doped ce0.45zr0.45re0.1 solid solutions were synthesized via reverse micro-emulsion method and the catalytic performance of the rh-supported catalysts was investigated in autothermal reforming of methane (atr). it was found that ch4 conversion went through a maximum as a function of oxygen storage capacity (osc) value of the support. higher osc will help to enhance the reactivity toward water-gas-shift (wgs) reaction, resulting higher h-2/co ratio. a striking correlation between osc and h-2/co ratio was observed, which presented a maximum for the rh/czla (3.4) and a minimum for the rh/cztb (2.6) catalysts. (c) 2009 elsevier b. v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | ceo2-zro2 solid-solutions ; hydrogen-production ; mixed oxides ; structural-properties ; syngas ; oxidation ; rh ; performance ; behavior ; support |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000264975200014 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/141375]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Cao, Lei,Ni, Changjun,Yuan, Zhongshan,et al. Correlation between catalytic selectivity and oxygen storage capacity in autothermal reforming of methane over Rh/Ce0.45Zr0.45RE0.1 catalysts (RE = La, Pr, Nd, Sm, Eu, Gd, Tb)[J]. catalysis communications,2009,10(8):1192-1195. |
| APA | Cao, Lei,Ni, Changjun,Yuan, Zhongshan,&Wang, Shudong.(2009).Correlation between catalytic selectivity and oxygen storage capacity in autothermal reforming of methane over Rh/Ce0.45Zr0.45RE0.1 catalysts (RE = La, Pr, Nd, Sm, Eu, Gd, Tb).catalysis communications,10(8),1192-1195. |
| MLA | Cao, Lei,et al."Correlation between catalytic selectivity and oxygen storage capacity in autothermal reforming of methane over Rh/Ce0.45Zr0.45RE0.1 catalysts (RE = La, Pr, Nd, Sm, Eu, Gd, Tb)".catalysis communications 10.8(2009):1192-1195. |
入库方式： OAI收割
来源：大连化学物理研究所
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