VIBRATIONAL EXCITATION OF OH(v <= 3) FROM THE REACTION OF O(D-1) + Si(CH3)(3)Cl
文献类型：期刊论文
| 作者 | Li Hongzhi; Wang Xuebin; Kong Fanao; Zhu Qihe |
| 刊名 | acta physico-chimica sinica
 |
| 出版日期 | 1993 |
| 卷号 | 9期号:4页码:447-449 |
| 关键词 | Intramolecular energy transfer IR emission spectroscopy Heavy atom effect Chlorotrimethylsilane |
| 英文摘要 | the vibrationally excited oh(v) from the reaction of o(d-1)+si(ch3)(3)cl was observed by uv lasre photolysis/ftir emission spectroscopy. the vibrational number was only up to 3 with a ratio of 1:0.3:0 1 for v=1:2:3. comparing this result with the similar reaction of o(d-1) + si(ch3)(4) which oh(v) vibrational number was high up to 4 with a ration of 1:1:1:0:3 for v=1:2:3:4 under the same experimental conditions, it was found that the substitution of cl for ch3 affected the extent of heavy si atom blooking the energy migratio in a molecule. this results identifies the prediction that the characteristic of electrons in central atom plays an important role in intramolecular energy transfer. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000207577600004 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/141380]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Inst Chem, State Key Lab Mol React Dynam, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li Hongzhi,Wang Xuebin,Kong Fanao,et al. VIBRATIONAL EXCITATION OF OH(v <= 3) FROM THE REACTION OF O(D-1) + Si(CH3)(3)Cl[J]. acta physico-chimica sinica,1993,9(4):447-449. |
| APA | Li Hongzhi,Wang Xuebin,Kong Fanao,&Zhu Qihe.(1993).VIBRATIONAL EXCITATION OF OH(v <= 3) FROM THE REACTION OF O(D-1) + Si(CH3)(3)Cl.acta physico-chimica sinica,9(4),447-449. |
| MLA | Li Hongzhi,et al."VIBRATIONAL EXCITATION OF OH(v <= 3) FROM THE REACTION OF O(D-1) + Si(CH3)(3)Cl".acta physico-chimica sinica 9.4(1993):447-449. |
入库方式： OAI收割
来源：大连化学物理研究所
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