3,6-Disubstituted Carbazole-Based Bisboronic Acids with Unusual Fluorescence Transduction as Enantioselective Fluorescent Chemosensors for Tartaric Acid
文献类型：期刊论文
| 作者 | Han, Feng1; Chi, Lina1; Liang, Xiaofen1; Ji, Shaomin1; Liu, Shasha2; Zhou, Fuke1; Wu, Yubo1; Han, Keli3; Zhao, Jianzhang1; James, Tony D.4 |
| 刊名 | journal of organic chemistry
 |
| 出版日期 | 2009-02-06 |
| 卷号 | 74期号:3页码:1333-1336 |
| 英文摘要 | carbazole-based bisboronic acids were found to be enantioselective fluorescent sensors for tartaric acid. the fluorescence response toward the enantiomers of tartaric acid at neutral ph displayed enhancement/diminishment. the sensor displays an unusual fluorescence intensity-ph relationship with diminished emission at acidic ph but. enhanced emission at basic ph. photoinduced electron transfer (pet) from the fluorophore to the protonated amine/phenylboronic acid unit is proposed to be responsible for this effect, which is rationalized by density functional theory (dft) calculations. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, organic |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | chiral-anion recognition ; teaching old indicators ; boronic acid ; enantiomeric excess ; reporter compounds ; sugar acids ; sensors ; molecules ; saccharides ; receptors |
| 收录类别 | SCI ; IC |
| 语种 | 英语 |
| WOS记录号 | WOS:000263004300048 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/141472]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Dalian Univ Technol, Sch Chem Engn, State Key Lab Fine Chem, Dalian 116012, Peoples R China 2.Dalian Univ Technol, Sch Phys & Optoelect Technol, Dalian 116012, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 4.Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England |
| 推荐引用方式 GB/T 7714 | Han, Feng,Chi, Lina,Liang, Xiaofen,et al. 3,6-Disubstituted Carbazole-Based Bisboronic Acids with Unusual Fluorescence Transduction as Enantioselective Fluorescent Chemosensors for Tartaric Acid[J]. journal of organic chemistry,2009,74(3):1333-1336. |
| APA | Han, Feng.,Chi, Lina.,Liang, Xiaofen.,Ji, Shaomin.,Liu, Shasha.,...&James, Tony D..(2009).3,6-Disubstituted Carbazole-Based Bisboronic Acids with Unusual Fluorescence Transduction as Enantioselective Fluorescent Chemosensors for Tartaric Acid.journal of organic chemistry,74(3),1333-1336. |
| MLA | Han, Feng,et al."3,6-Disubstituted Carbazole-Based Bisboronic Acids with Unusual Fluorescence Transduction as Enantioselective Fluorescent Chemosensors for Tartaric Acid".journal of organic chemistry 74.3(2009):1333-1336. |
入库方式： OAI收割
来源：大连化学物理研究所
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