Synthesis and Biological Activities of Xyloglucan Trisaccharides
文献类型：期刊论文
| 作者 | Liu Hong-Mei1,3; Bai Xue-Fang1; Du Yu-Guang1; Du Yu-Guo2,3 |
| 刊名 | chemical journal of chinese universities-chinese
 |
| 出版日期 | 2009-12-10 |
| 卷号 | 30期号:12页码:2396-2399 |
| 关键词 | Xyloglucan Oligosaccharide Tobacco Growth regulator |
| 英文摘要 | native xyloglucan oligosaccharides are a kind of growth regulator in plant development. a xyloglucan trisaccharide: alpha-d-xylopyranosyl-(1, 6) -beta-d-glucopyranosyl-(1, 4)-d-glucopyranose (1) and its derivatives were synthesized by three monosaccharide units. glycosylation of isopropyl 2, 3-di-o-acetyl-4, 6-o-benzylidene-1-thio-beta-d-glucopyranoside (3) as the donor with 4-methoxyphenyl 2,3 6-tri-o-benzoyl-beta-d-glucopyranoside(4) gave disaccharide(5). deprotection of 4,6-o-benzylidene of compound 5 gave 6 as disaccharide acceptor. then coupling of isopropyl 2,3 4-tri-o-benzyl-1-thio-beta-d-xylopyranoside(2) with 6 afforded alpha and beta trisaccharides(7) and separation of compound 7 gave 8(alpha) and 9 (beta). global deprotection of compound 8 obtained trisaccharide 1. the whole route involves five steps and the total yield is 15%. synthetic trisaccharides were added to the culture medium to detect their effects on tobacco growth. the results show that three synthesized oligosaccharides promote the growth of tobacco at the level of 1 mg/l. these results suggest that synthesized trisaccharides may be good prospects for the application in the control of plant growth. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, multidisciplinary |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | plant-cell wall ; repeating unit ; oligosaccharides ; growth ; elongation ; antigen |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000273792900014 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/141485]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Nat Prod & Glycoconjugate Res Grp 1805, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Ecoenvironm Sci Res Ctr, State Key Lab Environm Chem & Ecotoxicol, Beijing 100085, Peoples R China 3.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu Hong-Mei,Bai Xue-Fang,Du Yu-Guang,et al. Synthesis and Biological Activities of Xyloglucan Trisaccharides[J]. chemical journal of chinese universities-chinese,2009,30(12):2396-2399. |
| APA | Liu Hong-Mei,Bai Xue-Fang,Du Yu-Guang,&Du Yu-Guo.(2009).Synthesis and Biological Activities of Xyloglucan Trisaccharides.chemical journal of chinese universities-chinese,30(12),2396-2399. |
| MLA | Liu Hong-Mei,et al."Synthesis and Biological Activities of Xyloglucan Trisaccharides".chemical journal of chinese universities-chinese 30.12(2009):2396-2399. |
入库方式： OAI收割
来源：大连化学物理研究所
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