Crystal structure and thermochemical properties of 1-dodecylamine hydrochloride (C(12)H(28)NCl)(s)
文献类型：期刊论文
| 作者 | Kong, Yu-Xia1; Di, You-Ying1; Zhang, Ya-Qian1; Yang, Wei-Wei1; Tan, Zhi-Cheng2 |
| 刊名 | thermochimica acta
 |
| 出版日期 | 2009-11-10 |
| 卷号 | 495期号:1-2页码:33-37 |
| 关键词 | 1-Dodecylamine hydrochloride X-ray crystallography Lattice potential energy Isoperibol solution-reaction calorimetry Enthalpy of dissolution Hydration enthalpy |
| 英文摘要 | crystal structure of 1-dodecylamine hydrochloride (c(12)h(28)ncl)(s) has been determined by an x-ray crystallography. lattice potential energy and the molar volumes of the solid compound and its cation were respectively obtained. the enthalpy of dissolution of the compound was measured by an isoperibol solution-reaction calorimeter at 298.15 k. the molar enthalpy of dissolution at infinite dilution was determined to be delta(s)h(m)(theta) = 30.36 kj mol(-1), and relative apparent molar enthalpies (phi(l)) relative partial molar enthalpies (l(2)) of the compound and relative partial molar enthalpies (l(1)) of the solvent (double distilled water) at different concentrations in (mol kg(-1)) were obtained through fitted multiple regression equation by means of pitzer's theory. finally, hydration enthalpies of the substance and its cation were calculated by designing a thermochemical cycle in accordance with lattice potential energy and the molar enthalpy of dissolution at infinite dilution (delta(s)h(m)(theta)). (c) 2009 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, analytical ; chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | temperature heat-capacities ; standard molar enthalpy ; thermodynamics ; lattice ; calorimetry ; chloride ; volumes ; metal |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000271926200006 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/141495]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Liaocheng Univ, Coll Chem & Chem Engn, Liaocheng 252029, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Thermochem Lab, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Kong, Yu-Xia,Di, You-Ying,Zhang, Ya-Qian,et al. Crystal structure and thermochemical properties of 1-dodecylamine hydrochloride (C(12)H(28)NCl)(s)[J]. thermochimica acta,2009,495(1-2):33-37. |
| APA | Kong, Yu-Xia,Di, You-Ying,Zhang, Ya-Qian,Yang, Wei-Wei,&Tan, Zhi-Cheng.(2009).Crystal structure and thermochemical properties of 1-dodecylamine hydrochloride (C(12)H(28)NCl)(s).thermochimica acta,495(1-2),33-37. |
| MLA | Kong, Yu-Xia,et al."Crystal structure and thermochemical properties of 1-dodecylamine hydrochloride (C(12)H(28)NCl)(s)".thermochimica acta 495.1-2(2009):33-37. |
入库方式： OAI收割
来源：大连化学物理研究所
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