Time-Resolved Dynamics of NO2 in Its Conical Intersection Region
文献类型：期刊论文
| 作者 | Liu, Benkang1,2; Zhu, Jingyi1,2; Wang, Bingxing1,2; Wang, Yanqiu1; Wang, Li1 |
| 刊名 | journal of physical chemistry a
 |
| 出版日期 | 2009-12-17 |
| 卷号 | 113期号:50页码:13839-13844 |
| 英文摘要 | photodissociation dynamics of no2 ill its conical intersection region have been explored experimentally oil a real-time, scale by time-of-flight mass spectrometry excited at 400.6 nm and probed by 801 6 nm femtosecond lager pulses, different dynamical behaviors of both the parent ion no2+ and the fragment ion no+ have been observed under parallel and perpendicular pump-probe laser polarization configurations. distinct oscillations in no2+ and no+ signals are observed when laser polarizations of pump and probe are perpendicular to each other, whereas the oscillations become blurry when the laser polarizations are parallel the observed transient signals imply that the dissociation mechanism of no2 in the a(2)b(2) excited state needed to be reconsidered on the basis of our observation, rydberg states play important roles in the ultrafast dissociation dynamics of no2. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical ; physics, atomic, molecular & chemical |
| 研究领域[WOS] | chemistry ; physics |
| 关键词[WOS] | potential-energy surfaces ; photoelectron-spectroscopy ; dissociation dynamics ; states ; photodissociation ; ionization ; photoion |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000272559800002 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/141515]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Benkang,Zhu, Jingyi,Wang, Bingxing,et al. Time-Resolved Dynamics of NO2 in Its Conical Intersection Region[J]. journal of physical chemistry a,2009,113(50):13839-13844. |
| APA | Liu, Benkang,Zhu, Jingyi,Wang, Bingxing,Wang, Yanqiu,&Wang, Li.(2009).Time-Resolved Dynamics of NO2 in Its Conical Intersection Region.journal of physical chemistry a,113(50),13839-13844. |
| MLA | Liu, Benkang,et al."Time-Resolved Dynamics of NO2 in Its Conical Intersection Region".journal of physical chemistry a 113.50(2009):13839-13844. |
入库方式： OAI收割
来源：大连化学物理研究所
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