Preparation of alkali-resistant, Sil-1 encapsulated nickel catalysts for direct internal reforming-molten carbonate fuel cell
文献类型：期刊论文
| 作者 | Zhou, Jinglin1; Zhang, Xiongfu1; Zhang, Jian1; Liu, Haiou1; Zhou, Li2; Yeung, KingLun3 |
| 刊名 | catalysis communications
 |
| 出版日期 | 2009-08-25 |
| 卷号 | 10期号:14页码:1804-1807 |
| 关键词 | Core-shell catalyst Nickel catalyst Fuel cell Methane steam reforming Catalyst deactivation Zeolite membrane |
| 英文摘要 | a thin layer of silicalite-1 zeolite membrane was grown on the surface of ni/sio(2) and ni/al(2)o(3) catalyst beads after seeding and secondary regrowth to create core-shell catalysts that are resistant to alkali poisoning from direct internal reforming-mol ten carbonate fuel cell (dir-mcfc). the zeolite shell thickness was optimized to prevent poisoning and minimize diffusion resistance. an out-of-cell test was designed to simulate the fuel cell operating conditions, which showed that the new core-shell catalysts maintained a high activity similar to the original fresh catalyst in spite of the exposure to alkali vapor at high temperature. the conventional ni/sio(2) and ni/al(2)o(3) catalysts suffered higher than 80% decrease in activity for steam reforming of methane reaction (srm). (c) 2009 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | porous ceramic membranes ; permeation properties ; synthesis parameters ; growth ; mcfc ; microstructure ; isoparaffins ; h-2 |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000269664200005 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/141519]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Dalian Univ Technol, State Key Lab Fine Chem, Sch Chem Engn & Technol, Dalian 116012, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Fuel Cell Res & Dev Ctr, Dalian 116023, Peoples R China 3.Hong Kong Univ Sci & Technol, Dept Chem & Biomol Engn, Kowloon, Hong Kong, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhou, Jinglin,Zhang, Xiongfu,Zhang, Jian,et al. Preparation of alkali-resistant, Sil-1 encapsulated nickel catalysts for direct internal reforming-molten carbonate fuel cell[J]. catalysis communications,2009,10(14):1804-1807. |
| APA | Zhou, Jinglin,Zhang, Xiongfu,Zhang, Jian,Liu, Haiou,Zhou, Li,&Yeung, KingLun.(2009).Preparation of alkali-resistant, Sil-1 encapsulated nickel catalysts for direct internal reforming-molten carbonate fuel cell.catalysis communications,10(14),1804-1807. |
| MLA | Zhou, Jinglin,et al."Preparation of alkali-resistant, Sil-1 encapsulated nickel catalysts for direct internal reforming-molten carbonate fuel cell".catalysis communications 10.14(2009):1804-1807. |
入库方式： OAI收割
来源：大连化学物理研究所
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