Ruthenium-Catalyzed Nucleophilic Allylic Substitution Reactions from beta-Silylated Allylic Carbonates
文献类型：期刊论文
| 作者 | Zhang, Hui-Jun1,2; Demerseman, Bernard2; Toupet, Loic2; Xi, Zhenfeng1; Bruneau, Christian2 |
| 刊名 | organometallics
 |
| 出版日期 | 2009-09-14 |
| 卷号 | 28期号:17页码:5173-5182 |
| 英文摘要 | the trans addition of hsiet(3) to propargylic ethyl carbonates catalyzed by the ruthenium complex [ru(c(5)me(5))(mecn)(3)][pf(6)], 1, leads to h(2)c=c(siet(3))ch(r)oco(2)et (r = h, me, pr(n), or ph) derivatives as allylic substrates for subsequent ruthenium-catalyzed nucleophilic allylic substitution reactions. ruthenium catalysts based on a [ru(c(5)me(5))(2-quinolinecarboxylato)] or [ru(c(5)me(5))(2,2'-bipyridine)](+) fragment are more efficient than 1 for access to various h(2)c=c(siet(3))ch(r)nufunctionalized vinylsilanes (r = h, me; nuh = secondary amine, phenol, dimethylmalonate, methanol). new [ru(c(5)me(5))(2-quinolinecarboxylato)(eta(3-)allyl)](+) cationic ruthenium(iv) intermediates are characterized, and experiments using a deuteriurn-labelcd allylic carbonate provide evidence for a regioselectivity arising from the presence of the 2-quinolinecarboxylato (n,o)-chelate. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, inorganic & nuclear ; chemistry, organic |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | terminal alkynes ; x-ray ; complexes ; efficient ; hydrosilylation ; derivatives ; alkylation ; metathesis ; activation ; reactivity |
| 收录类别 | SCI ; IC |
| 语种 | 英语 |
| WOS记录号 | WOS:000269424200036 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/141520]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Peking Univ, BNLMS, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Coll Chem, Beijing 100871, Peoples R China 2.Univ Rennes 1, CNRS, UMR 6226, F-35042 Rennes, France |
| 推荐引用方式 GB/T 7714 | Zhang, Hui-Jun,Demerseman, Bernard,Toupet, Loic,et al. Ruthenium-Catalyzed Nucleophilic Allylic Substitution Reactions from beta-Silylated Allylic Carbonates[J]. organometallics,2009,28(17):5173-5182. |
| APA | Zhang, Hui-Jun,Demerseman, Bernard,Toupet, Loic,Xi, Zhenfeng,&Bruneau, Christian.(2009).Ruthenium-Catalyzed Nucleophilic Allylic Substitution Reactions from beta-Silylated Allylic Carbonates.organometallics,28(17),5173-5182. |
| MLA | Zhang, Hui-Jun,et al."Ruthenium-Catalyzed Nucleophilic Allylic Substitution Reactions from beta-Silylated Allylic Carbonates".organometallics 28.17(2009):5173-5182. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。