Enhancing antifouling property of polysulfone ultrafiltration membrane by grafting zwitterionic copolymer via UV-initiated polymerization
文献类型:期刊论文
作者 | Yu, Haijun1,2; Cao, Yiming1; Kang, Guodong1; Liu, Jianhui1; Li, Meng1; Yuan, Quan1 |
刊名 | journal of membrane science
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出版日期 | 2009-10-15 |
卷号 | 342期号:1-2页码:6-13 |
关键词 | Surface modification UV-initiated grafting polymerization Zwitterionic copolymer Antifouling |
英文摘要 | a new kind of zwitterionic molecule, [3-(methacryloylamino)propyl]-dimethyl (3-sulfopropyl) ammonium hydroxide inner salt (mpdsah) was grafted onto polysulfone (psf) ultrafiltration membrane surface using benzophenone (bp) as the initiator to improve the antifouling property. polymer chain scission was suppressed by h-abstraction from methyl groups under long-wavelength uv irradiation (lambda > 300 nm), which avoided the photodegradation of psf ultrafiltration membrane. the effects of mpdsah concentration, uv irradiation time and bp concentration on grafting degree (gd) and the improvement of membrane antifouling properties were investigated, respectively. attenuated total reflectance fourier transform infrared spectroscopy (ftir/atr) and scanning electron micrograph (sem) were used to characterize the chemical and morphological changes of the membrane surface. static contact angle (ca) measurements showed that the hydrophilicity of mpdsah-modified psf ultrafiltration membranes was enhanced with the increase of grafting degree. the flux of pure water decreased slightly after modification, while the rejection to bovine serum albumin (bsa) increased. the improvement of antifouling property for mpdsah-modified membrane was accordant with the increase of grafting degree. in addition, compared to psf membrane, the modified membranes could maintain a higher water flux in wide ph range. (c) 2009 elsevier b.v. all rights reserved. |
WOS标题词 | science & technology ; technology ; physical sciences |
类目[WOS] | engineering, chemical ; polymer science |
研究领域[WOS] | engineering ; polymer science |
关键词[WOS] | polypropylene microporous membranes ; low-temperature plasma ; surface modification ; uf membranes ; polyethersulfone ; performance ; adsorption ; monomer ; functionalization ; immobilization |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000269678400002 |
公开日期 | 2015-11-17 |
源URL | [http://159.226.238.44/handle/321008/141537] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Yu, Haijun,Cao, Yiming,Kang, Guodong,et al. Enhancing antifouling property of polysulfone ultrafiltration membrane by grafting zwitterionic copolymer via UV-initiated polymerization[J]. journal of membrane science,2009,342(1-2):6-13. |
APA | Yu, Haijun,Cao, Yiming,Kang, Guodong,Liu, Jianhui,Li, Meng,&Yuan, Quan.(2009).Enhancing antifouling property of polysulfone ultrafiltration membrane by grafting zwitterionic copolymer via UV-initiated polymerization.journal of membrane science,342(1-2),6-13. |
MLA | Yu, Haijun,et al."Enhancing antifouling property of polysulfone ultrafiltration membrane by grafting zwitterionic copolymer via UV-initiated polymerization".journal of membrane science 342.1-2(2009):6-13. |
入库方式: OAI收割
来源:大连化学物理研究所
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