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Enhancing antifouling property of polysulfone ultrafiltration membrane by grafting zwitterionic copolymer via UV-initiated polymerization

文献类型:期刊论文

作者Yu, Haijun1,2; Cao, Yiming1; Kang, Guodong1; Liu, Jianhui1; Li, Meng1; Yuan, Quan1
刊名journal of membrane science
出版日期2009-10-15
卷号342期号:1-2页码:6-13
关键词Surface modification UV-initiated grafting polymerization Zwitterionic copolymer Antifouling
英文摘要a new kind of zwitterionic molecule, [3-(methacryloylamino)propyl]-dimethyl (3-sulfopropyl) ammonium hydroxide inner salt (mpdsah) was grafted onto polysulfone (psf) ultrafiltration membrane surface using benzophenone (bp) as the initiator to improve the antifouling property. polymer chain scission was suppressed by h-abstraction from methyl groups under long-wavelength uv irradiation (lambda > 300 nm), which avoided the photodegradation of psf ultrafiltration membrane. the effects of mpdsah concentration, uv irradiation time and bp concentration on grafting degree (gd) and the improvement of membrane antifouling properties were investigated, respectively. attenuated total reflectance fourier transform infrared spectroscopy (ftir/atr) and scanning electron micrograph (sem) were used to characterize the chemical and morphological changes of the membrane surface. static contact angle (ca) measurements showed that the hydrophilicity of mpdsah-modified psf ultrafiltration membranes was enhanced with the increase of grafting degree. the flux of pure water decreased slightly after modification, while the rejection to bovine serum albumin (bsa) increased. the improvement of antifouling property for mpdsah-modified membrane was accordant with the increase of grafting degree. in addition, compared to psf membrane, the modified membranes could maintain a higher water flux in wide ph range. (c) 2009 elsevier b.v. all rights reserved.
WOS标题词science & technology ; technology ; physical sciences
类目[WOS]engineering, chemical ; polymer science
研究领域[WOS]engineering ; polymer science
关键词[WOS]polypropylene microporous membranes ; low-temperature plasma ; surface modification ; uf membranes ; polyethersulfone ; performance ; adsorption ; monomer ; functionalization ; immobilization
收录类别SCI
语种英语
WOS记录号WOS:000269678400002
公开日期2015-11-17
源URL[http://159.226.238.44/handle/321008/141537]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Yu, Haijun,Cao, Yiming,Kang, Guodong,et al. Enhancing antifouling property of polysulfone ultrafiltration membrane by grafting zwitterionic copolymer via UV-initiated polymerization[J]. journal of membrane science,2009,342(1-2):6-13.
APA Yu, Haijun,Cao, Yiming,Kang, Guodong,Liu, Jianhui,Li, Meng,&Yuan, Quan.(2009).Enhancing antifouling property of polysulfone ultrafiltration membrane by grafting zwitterionic copolymer via UV-initiated polymerization.journal of membrane science,342(1-2),6-13.
MLA Yu, Haijun,et al."Enhancing antifouling property of polysulfone ultrafiltration membrane by grafting zwitterionic copolymer via UV-initiated polymerization".journal of membrane science 342.1-2(2009):6-13.

入库方式: OAI收割

来源:大连化学物理研究所

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