Rh/MgO/Ce0.5Zr0.5O2 supported catalyst for autothermal reforming of methane: The effects of ceria-zirconia doping
文献类型：期刊论文
| 作者 | Yuan, Zhongshan1; Ni, Changjun1; Zhang, Chunxi1; Gao, Diannan1; Wang, Shudong1; Xie, Yuming2; Okada, Akira2 |
| 刊名 | catalysis today
 |
| 出版日期 | 2009-08-15 |
| 卷号 | 146期号:1-2页码:124-131 |
| 关键词 | Methane autothermal reforming Supported Rh/MgO/Ce0.5Zr0.5O2 catalyst Ceria-zirconia |
| 英文摘要 | the supported rh/mgo/ce0.5zr0.5o2 catalysts were developed for autothermal reforming of methane. the effects of ceria-zirconia addition on the rh catalyst were characterized with bet, xrd, saed, hrem and tpr. the catalytic performance was evaluated on a flow through reactor. results showed that the addition of ceria-zirconia enhanced the catalyst stability due to the interactions between ceria-zirconia, mgo promoter and the active component rh. meanwhile, the selectivity towards hydrogen in reformate was also boosted because of the increased water gas shift activity by the mixed oxides. the results also showed that the structural properties, the textural properties and the redox properties of ceria-zirconia had great influences on the catalyst performance, especially on the catalyst stability. formations of single phase solid solution, larger pore size as well as ce/zr ratio at 1/1 were more desirable for ceria-zirconia dopant. as a result, one of the optimized honeycomb catalysts with the composition of 0.3% rh/2.5% mgo/43.2% ce(0.5)zr(0.5)o2/54.0% cordierite (wt.%) has been continually operated at 800 degrees c up to 2000 h without deactivation. (c) 2009 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | oxygen storage capacity ; partial oxidation ; low-temperature ; natural-gas ; hydrogen-production ; mixed oxides ; small-scale ; fuel-cells ; gasoline ; hydrocarbons |
| 收录类别 | SCI ; ISTP |
| 语种 | 英语 |
| WOS记录号 | WOS:000269659000020 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/141539]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Lab Adv Chem Engn, Dalian 116023, Peoples R China 2.Corning Inc, Sci & Technol, Corning, NY 14831 USA |
| 推荐引用方式 GB/T 7714 | Yuan, Zhongshan,Ni, Changjun,Zhang, Chunxi,et al. Rh/MgO/Ce0.5Zr0.5O2 supported catalyst for autothermal reforming of methane: The effects of ceria-zirconia doping[J]. catalysis today,2009,146(1-2):124-131. |
| APA | Yuan, Zhongshan.,Ni, Changjun.,Zhang, Chunxi.,Gao, Diannan.,Wang, Shudong.,...&Okada, Akira.(2009).Rh/MgO/Ce0.5Zr0.5O2 supported catalyst for autothermal reforming of methane: The effects of ceria-zirconia doping.catalysis today,146(1-2),124-131. |
| MLA | Yuan, Zhongshan,et al."Rh/MgO/Ce0.5Zr0.5O2 supported catalyst for autothermal reforming of methane: The effects of ceria-zirconia doping".catalysis today 146.1-2(2009):124-131. |
入库方式： OAI收割
来源：大连化学物理研究所
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