Oxidative Dehydrogenation of 9,10-Dihydroanthracene Catalyzed by 2,3-Dichloro-5,6-dicyano-1,4-benzoquinone/NaNO2
文献类型:期刊论文
作者 | Zhang Wei1,2; Ma Hong1; Zhou Lipeng3; Miao Hong1; Xu Jie1 |
刊名 | chinese journal of catalysis
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出版日期 | 2009-02-01 |
卷号 | 30期号:2页码:86-88 |
关键词 | 2 sodium nitrite 9 oxidative dehydrogenation 3-dichloro-5 10-dihydroanthracene 6-dicyano-1 4-benzoquinone |
英文摘要 | a catalyst for the oxidative dehydrogenation of 9, 10-dihydroanthracene to anthracene comprising 2,3-dichloro -5,6-dicyano-1,4-benzoquinone (ddq) and nano2 showed high catalytic efficiency, with >99% conversion of 9, 10-dilaydroanthracene and 99% selectivity for anthracene at 120 degrees c under 1.3 mpa o-2 for 8 h. the reaction mechanism was investigated by ft-ir, h-1 nmr, and c-13 nmr. the two redox couples ddq/ddqh(2) and no2/no were coupled in the presence of o-2 to create a catalytic cycle for the oxidative dehydrogenation of 9, 10-dihydroanthracene to anthracene. |
WOS标题词 | science & technology ; physical sciences ; technology |
类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
研究领域[WOS] | chemistry ; engineering |
关键词[WOS] | aerobic oxidation ; hydrocarbons ; oxygenation ; alcohols ; dioxygen |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000264168700002 |
公开日期 | 2015-11-17 |
源URL | [http://159.226.238.44/handle/321008/141583] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China 3.Zhengzhou Univ, Inst Catalysis, Dept Chem, Zhengzhou 450001, Henan, Peoples R China |
推荐引用方式 GB/T 7714 | Zhang Wei,Ma Hong,Zhou Lipeng,et al. Oxidative Dehydrogenation of 9,10-Dihydroanthracene Catalyzed by 2,3-Dichloro-5,6-dicyano-1,4-benzoquinone/NaNO2[J]. chinese journal of catalysis,2009,30(2):86-88. |
APA | Zhang Wei,Ma Hong,Zhou Lipeng,Miao Hong,&Xu Jie.(2009).Oxidative Dehydrogenation of 9,10-Dihydroanthracene Catalyzed by 2,3-Dichloro-5,6-dicyano-1,4-benzoquinone/NaNO2.chinese journal of catalysis,30(2),86-88. |
MLA | Zhang Wei,et al."Oxidative Dehydrogenation of 9,10-Dihydroanthracene Catalyzed by 2,3-Dichloro-5,6-dicyano-1,4-benzoquinone/NaNO2".chinese journal of catalysis 30.2(2009):86-88. |
入库方式: OAI收割
来源:大连化学物理研究所
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