Green Epoxidation of alpha,beta-Unsaturated Ketones
文献类型：期刊论文
| 作者 | Zhang Aiping1,2; Gao Shuang1; Xu Jie1; Xi Zuwei1; Hu Xinquan3 |
| 刊名 | chinese journal of catalysis
 |
| 出版日期 | 2009 |
| 卷号 | 30期号:1页码:69-72 |
| 关键词 | alpha epoxidation quaternary ammonium heteropolyphosphatotungstate beta-unsaturated ketone |
| 英文摘要 | in the presence of h(2)o(2) the epoxidation of alpha,beta-unsaturated ketones catalyzed by quaternary ammonium heteropolyphosphatotungstate was studied. the factors such as different solvents, reaction temperature, the catalyst amount, reaction time, and the substrate concentration were investigated. it was found that the epoxidation of alpha,beta-unsaturated ketones was easily performed in this catalytic system. under the optimized reaction conditions an epoxy-4-methyl-3-penten-2-one yield of 87% was obtained. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | phase-transfer catalysis ; hydrogen-peroxide ; carbonyl-compounds ; efficient ; heteropolyphosphatotungstate ; olefins ; oxide |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000263444300015 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/141584]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China 3.Zhejiang Univ Technol, Coll Chem Engn & Mat Sci, Hangzhou 310000, Zhejiang, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang Aiping,Gao Shuang,Xu Jie,et al. Green Epoxidation of alpha,beta-Unsaturated Ketones[J]. chinese journal of catalysis,2009,30(1):69-72. |
| APA | Zhang Aiping,Gao Shuang,Xu Jie,Xi Zuwei,&Hu Xinquan.(2009).Green Epoxidation of alpha,beta-Unsaturated Ketones.chinese journal of catalysis,30(1),69-72. |
| MLA | Zhang Aiping,et al."Green Epoxidation of alpha,beta-Unsaturated Ketones".chinese journal of catalysis 30.1(2009):69-72. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。